室内空气中甲醛在ACF上的衍生反应动力学及其定量关系的研究.pdfVIP

学兔兔 100 江苏建筑 2010年第6期(总第 138期) 室内空气中甲醛在ACF上的衍生反应动力学及其定量关系的研究 王雨群”，王正萍 (’江苏省建筑科学研究院，江苏南京 210008； 南京理工大学化工学院，江苏南京 210094) 『摘 要】 文章在对ACF的纳米空间结构及其栽体功能特性以及ACF纳米结构上甲醛的衍生反应及其吸附／解吸原理，进 行深入研究基础上，揭示了室内空气q-甲醛在ACF上的吸附与解析动力学过程。根据Langmuir-Rideal定理，描述了甲醛与 PFBHA—HCHO反应定量关系：推导出PFBHA—HCHO肟化合物浓度的反应速率与室内空气中甲醛浓度之间的一级反应线 性回归方程，为定量检测室内空气中甲醛提供了理论依据。 [关键词】 活性碳纤维(ACV)；邻一五氟苄基羟胺；衍生反应动力学；定量关系；室内空气中甲醛； [中图分类-~]TQO13 [文献标识码]A [文章编号]1005—6270(2010)06—0100—03 Study on the Kinetics of Derivative Reaction and the Quantitative Relationship of Formaldehyde in Indoor Air on-ACF WANG Yun-qung 、 WANG Zheng-pin~ (1．Jiangsu Research Institute of Building Science，Nanjing Jiangsu 210008 China； 2．School of Chemeial Engineering，Nanjing University of Science＆Technology，Nanjing Jiangsu 210094 China) Abstract： Based on study on the characteristics of the nano pore structure and the special carrier Of ACF and the surface characteristic of ACF and the principle of its adsorption／desorption，the dynamic process of adsorp- tion／desorption of formaldehyde in indoor air on ACF fiber were pointed out． According to Langmuir—Rideal mechanism，the of PFBHA-HCHO oxime with formaldehyde was described．The linear regression equation the primary reaction of the formaldehyde concentration in indoor air with PFBHA —HCHO oxime has been de— rived，the theory of quantitative analysis formaldehyde in indoor air was provided． Key words：activated carbon fiber(AC ；O一(2，3，4，5，6-pentafluorobenzy1)hydroxylamine(PFBHA)；derivati— zation；dynamic process；quantitative relationship；formaldehyde in indoor air 甲醛是原浆毒物，对人体产生的毒性效应[1-7 3包括：呼 同相微萃取技术(SPME)虽然是