电阻率法研究早期水泥净浆孔结构的演变过程.pdfVIP

学兔兔 第34卷第5期 土木 建 筑 与 环 境 工 程 Journal of Civil。Architectural Environmental Engineering Vo1．34 NO．5 2O12年1O月 0ct．2O12 doi：10．3969／j．issn．1674—4764．2012．05．024 电阻率法研究早期水泥净浆孔结构的演变过程 刘志勇 ，张云升 ，孙国文 ，姜 骞 ，张文华 (东南大学a．材料科学与工程学院；b．江苏省土木工程材料重点实验室，南京 211189) 摘 要：采用无电极电阻率法原位连续监测 3种水灰比(0．23、0．35和0．53)水泥净浆早期水化过 程中电阻率的变化全过程，同时结合等温量热仪测试的水化程度，建立水泥净浆随时间发展过程中 浆体电阻率与孔结构发展的定量关系。结果表明：根据电阻率及其微分曲线的变化规律可以把水 泥水化过程分为4个阶段：溶解期、诱导期、加速期和减速期。水灰比越低，毛细孔隙率和收缩因子 变小，曲折因子变大，致使浆体电阻率升高，而孔溶液电阻率却下降。 关键词：水泥水化；电阻率；孔结构；逾渗阈值 中图分类号：TU502 文献标志码：A 文章编号：1674—4764【2012)05—0148—06 Resistivity Method for Monitoring the Early Age Pore Structure Evolution of Cement Paste LIU Zhiyong。，。，ZHANG Yunsheng。。，SUN Guowen。， ，JIANG Qian。。，ZHANG Wenhua。，。 (a．Jiangsu Key Laboratory for Construction Materials； b．College of Materials Science and Engineering，Southeast University，Nanjing 211189，P．R．China) Abstract：The changes of electrical resistivity with time of cement pastes with water to cement ratio of 0．23， 0．35 and 0．53 were in situ continuously monitored by using electrodeless resistivity apparatus．Isothermal conduction calorimeter was also used to measure the hydration degree．The quantitative relationship between electrical resistivity evolution of paste and development of pore structure was proposed during hydration process．The results show that four stages(dissolution，induction，acceleration and deceleration) are identified according to the characteristics of electrical resistivity and its differential resistivity curves．In addition，a lower water to cemen