氨基磺酸盐系高效减水剂的改性研究.pdfVIP

维普资讯 学兔兔 第29卷 第2期 重 庆 建 筑 大 学 学报 Vo1．29 No．2 2007年 4月 Journal of Chongqing Jianzhu University Apr．2007 氨基磺酸盐系高效减水剂的改性研究 张智强 ， 钱中秋 ， 饶枭宇 ， 丁 虹。 (1．重庆大学 材料科学与工程学院，重庆 400045；2．常州市建筑科学研究院有限公司，江苏常州 213015；3．西华大学 建筑 与土木工程学院，四J1I成都 610039) 摘要：氨基磺酸盐系减水剂具有高减水率、抑制混凝土塌落度经时损失等优点，但泌水严重，~~-Vl了其在 混凝土中的应用。本文根据“分子设计”原则 ，通过单体 A和单体 U 引入适 当的官能团，对传统氨基磺 酸盐系高效减水剂进行改性，测试了产品对水泥净浆流动度、流动度经时损失和泌水率的影响。试验表 明，单体 A的改性效果优于单体 U，以 9 的单体 A 改性后 ，减水剂的分散性和分散保持性能好，泌水 率显著降低。 关键词：氨基磺酸盐系；改性；高性能减水剂 中图分类号：TU528．042．2 文献标识码：A 文章编号：1006—7329(2007)02--0116--03 Study on Modification of Amino--sulfonic Acid—based Water—reducer ZHANG Zi—qiang ，QIAN Zhong--qiu ～，RAO Xiao—yu ，DING Hong。 (1．College of Materials Science and Engineering，Chongqing University，Chongqing 400045，China；2．Changzhou Construction Re— search Institute Co．Ltd，Changzhou 213015，China；3．College of Architecture and Civil Engineering，Xihua University，Chengdu 610039，China) Abstract：Amino—sulfonic acid—based water—reducer is characterized by high water—reducing rate and restrai— ning the concrete mixture from slump loss with time．The application of amino—sulfonic acid— based water— reducer in concrete mixture was restricted due tO its high bleeding．Based on principles of molecular design，the traditional superp1asticizer of aminosulfonic acid series was modified by the suitable functional group introduced by monomer A and monomer U．The effects of such product on the fluidity，fluidity loss with time and bleed— ing rate of cement paste were tested．It was found that the modifying effect of monomer A for the superplastici— zer was better than that of monomer U．The dispensability and flow retainab