溶液聚合制备丙烯酸酯橡胶的研究.pdfVIP

# 72# 2010 38 10 * 1 1 1 1 1 1, 2 , , , , , ( 1长春工业大学教育部合成树脂与特种纤维工程研究中心, 吉林 长春 130012; 2 中国科学院长春应用化学研究 , 吉林 长春 130022) : , , ; ( BPO ), BPO, ; ( BA) ( EA) ( MA ), , ; , MA , : ; ; ; * Investigation of P reparation of A crylate Rubber w ith Solu tion P olym erization 1 1 1 1 1 1, 2 SUN Shu - lin , LI U Zhong - qiang , YAN G Bo , TAN Zh i- yong , ZHAN GM ing - yao , ZHAN GH u i- xuan ( 1 Research Center of theM inistry ofE ucation for Synthesize Resin an SpecialF iber, Changchun University of Technology, Jilin Changchun 130012; 2 Changchun Institute of Applie Chem istry, Ch inese Aca emy of Sciences, Jilin Changchun 130022, Ch ina) Abs tract: The relationsh ip bewt een the conversion an tmi e of butyl acrylate polym erization w ith the solution poly- merization metho w as investigate . The result show e that the increase of temperature w as beneficial to the mi provement of reactive rate, how ever, the conversion ecrease w ith the mi prove temperature. The reaction rate of polymerization mi - prove w ith the increase of benzoyl peroxi e( BPO) content w hich w as use as the in itiator. The ifference betw een the conversionsw ith varie BPO content w as not obvious. The copolymerization of butyl acrylate w ith ethyl acrylate ormethyl acrylate mi prove the reactive rate an the conversion ha no obvious ifference. M ethyl acrylate mi prove the reactive ratew hen its contentw as low er than 30wt% an the conversion i not vary significantly. K ey w ord s: acrylate