电催化氧化预处理苯酚丙酮废水实验研究.pdf

中国环境科学 2017,37(1) ：131~138 China Environmental Science 电催化氧化预处理苯酚丙酮废水实验研究 1* 1 2 2 2 2 陈月芳 ,樊 荣 ,滕科均 ,陈凯华 ,潘建通 ,迟金宝 (1.北京科技大学能源与环境工程学院;北京市工业典 型污染物资源化处理重点实验室,北京 100083 ；2.北京博汇特环保科技有限公司,北京 100102) 摘要：通过电极的选择,催化活性炭粒子电极的制备,应用电催化氧化技术对某炼油厂含苯酚丙酮的生产废水进行预处理研究.通过对 5 种 金属催化剂进行比较,最终选择锰离子作为活性炭粒子的催化剂,提高了粒子电极的催化活性.通过研究 4 种影响因素:槽电压、pH 值、曝 气量、水力停留时间,对 CODcr 去除效果的影响,得到最佳反应条件为:槽电压取值为 15V,进水 pH 值为 5.5~6.5,水力停留时间为 90min,曝气 3 2 量为 6m /(m ·h).在最优条件下,废水 CODcr 去除率可达到 80%,可生化性 BOD/COD 值从 0.07 上升到 0.43,很大程度上提高了废水的可生化 性.在优化的试验条件下,生产废水中的酚类、芳香烃和醛类、酮类物质浓度都能降解到 10mg/L 以下,作为苯酚丙酮废水预处理效果显著, 为后续生化处理提供了有利条件. 关键词： 电催化氧化；苯酚丙酮废水；预处理；可生化性 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2017)01-0131-08 Experimental study on pretreatment of phenol acetone wastewater by electro-catalytic oxidation. CHEN Yue-fang1*, 1 2 2 2 2 FAN Rong , TENG Ke-jun , CHEN Kai-hua , PAN Jian-tong , CHI Jin-bao (1.Beijing Key Laboratory of Resource- oriented Treatment of Industrial Pollutants, School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China ；2.Beijing Bo-hui-te Environment Technology Limited Company, Beijing 100102, China). China Environmental Science, 2017,37(1)：131~138 Abstract ：The application of electro-catalytic oxidation technology for the pretreatment of a certain refinery’s wastewater containing phenol acetone was studied. After selection and preparation, five different metal-loaded activated carbon particle electrodes and their catalytic activities were determined. Manganese ion was finally chosen as the activated carbon particle catalyst, improving the catalytic activity of the