CeF3对无压熔渗法制备TiC／Ni3Al复合材料的渗入工艺影响.pdfVIP

学兔兔 Mar．2009 铸 造 FOUNDRY VOI．58 NO．3 CeF3对无压熔渗法制备TiC／Ni3Al复合材料的 渗入工艺影响 何柏林，于影霞，缪燕平 (华东交通大学机电工程学院，江西南昌330013) 摘要：以化学纯镍粉、钛粉、铝粉、石墨粉为原料，采用燃烧合成方法置备了TiC／Ni3Al含孔预制件，用无压熔渗法制 备了Ni3A1熔渗TiC／Ni~Al复合材料，研究了ceF3对无压渗透工艺、渗透动力学及TiC／NiAl复合材料的微观组织、硬度的 影响。采用XRD和SEM分析了复合材料的相组成、微观结构。试验结果表明，无压熔渗法是制备致密的TiC／Ni l复合 材料的有效方法，添加适量稀土CeF ，可大大缩短渗透时间；在完成渗透获得致密组织的前提下，添加CeF，对 TiC／Ni3A1复合材料的硬度无显著影响；渗透后复合材料的组成相为Ni3Al和TiC两相，NiAl相和TiC颗粒结合良好；制备 的TiC／Ni~l复合材料的维氏硬度随TiC体积分数的增加而增加，w(CeF，)为0．6％， (TiC)分别为70％和80％时，复合材 料的维氏硬度平均值分别为HV 561和HV 653。 关键词：无压熔渗；稀土氟化物；复合材料；微观组织；硬度 中图分类号：G633．8 文献标识码：A 文章编号：100l一4977(2009)03—0237—04 Effect of CeF3 on Manufacturing of TiC／Ni3AI Composites by Using Pressureless Melt Infiltration Process HE BO—lin，YU Ying—xia，MIAO Yan—ping (School of MechanicalElectrical Engineering，East China Jiaotong University， Nanchang 33001 3，Jiangxi，China) Abstract：Porous TiC-Ni3A1 was synthesized by SHS(self-propagating high-temperature synthesis) method by using nickel，titanium。aIuminum and graphite powder of chemically pure reagent． Pressureless melt infiltration was used for preparing TiC／Ni I composites．Effects of CeF3 on the pressureless infiltration process。the infiltration kinetics and miCrOstructure，hardness of the composites were studied．XRD and SEM were used to analyze the phase identification and the microstructure．The results show that pressureless melt infiltration is an effective method to fabricate dense TIC，Ni AI composites．The infiltration time can be greatly decreased by adding suitably