CO2硬化法用水玻璃粘合剂改性的研究.pdfVIP

维普资讯 学兔兔 Ju1．2008 铸 造 VO1．57 NO．7 FOUNDRY ·717· CO2石更化法用水玻璃粘合剂改性的研究 许 进 (湛江广播电视大学，广东湛江524003) 摘要：提高CO 水玻璃砂粘结强度的关键在于抑制硬化过程中胶粒的过度长大，可行的途径是向水玻璃中引入能与水 玻璃起作用并能阻抑胶粒长大，而且对CO 硬化不引起、或少引起负面影响的物质。选择了含有—℃0ONa极性基的有 机合成物为1 改性树脂；含有H0— 20“极性基的有机合成物为2 改性树脂，含有一cONH 极性基的有机物为3 改性 树脂，作为改性剂的主干材料对水玻璃进行改性处理。试验结果表明，改性水玻璃尤其是1 改性树脂改性水玻璃18 与 普通水玻璃相比，明显提高常温下的粘结强度；显著改善热强度和高温强度；消除了800℃时的残留强度峰值。 关键词：CO：硬化；水玻璃；改性 中图分类号：TG221 文献标识码：A 文章编号：1001—4977(2008)07—0717—05 Research On Modification of Sodium Silicate Adhesive flOr CO Cured Sand Mold XU Jin (Zhanjiang TV University，Zhanjiang 524003，Guangdong，China) Abstract：The key to improve the bond strength of COrcured sodium silicate bonded sand mold is to restrict the growth of particles in the curing sodium silicate process，and the feasible way is to introduce a material，which can hinder the particle growth and has little or less negative influence on COz-cured process，into the sodium silicate．Three polar organic compounds，containing nCOONa， HO CH2OH and nCONH2，respectively，were chosen as 1 ，2 and 3 modified resins，respectively， which are the main materials of the modifiers to modify the sodium silicate．The experimental results show that for the sand molds bonded by the modified sodium silicates，particularly for the sand mold bonded by the 1 8 sodium silicate modified by 1 modified resin．the bond strength at room temperature is increased markedly as compared to ordinary sodium sili