玻璃组分对Fe—Ga合金熔体净化效果的影响.pdfVIP

学兔兔 Jun．2010 铸 造 VoI．59 NO．6 FOUNDRY 玻璃组分对Fe—Ga合金熔体净化效果的影响 高 翔，周建坤，李建国 (上海交通大学材料科学与工程学院，上海200240) 摘要：研究了在循环过热过程中不同组分玻璃净化剂对Fe 。Ga 和Fe Ga27 合金熔体获得的过冷度及其稳定性的影响。 结果表明，通过物理一化学复合净化作用，90％Na。Si—Ca+10％B20 (记作Na Si．Ca．B玻璃)可使Fe Ga 合金熔体在循环 过热过程中获得250K的稳定深过冷。但是，由于高温 (1 273 K)下Na．Si．Ca—B玻璃粘度过大，在循环过热过程中会 大量吸附液态Ga，会使Fe 5Gan5合金发生严重的Ga元素损耗。9．4％SIO2+84．6％Na2B407+6％CaO(记作Na．B．Si玻璃)的 净化机理与Na—Si—Ca—B玻璃相似，它能使Fe 5Gan 合金获得高达325K的深过冷，且由于其适中的高温粘性可有效避免 Ga元素损失的发生。 关键词：快速定向凝固；净化剂；Fe—Ga合金；过冷度；粘度 中图分类号：TG132 文献标识码：A 文章编号：1001—4977(2010)06—0607—04 E仟ect Of Glass Composition On Denucleation of Fe．Ga AIloy Melts GAO Xiang、ZHOU Jian．kun，LI Jian—guo (School of Material Science＆Engineering，Shanghai Jiaotong University，Shanghai 200240，China) Abstract：The obtained undercooling and its stability of Fe81Ga19 and Fe725Ga275 alloy melts are investigated by superheated under different denucleating glasses： 90％ NaSiCa + 1 0％ B2O3 (simplified as Na—Si-Ca—B)and 84．6％Na2B4O7+9．4％SiO2+6％CaO (simplified as Na．B—Si)．For Na—Si-Ca-B glass，the denucleating mechanism iS a comprehensively physicochemical process。by which stable undercoolings up to 250 K can be obtained during the superheating—cooling cycles． However，Fe725Ga2z5 alloy has a great gallium loss when using Na—Si—Ca-B as the glass slag．The reason is that Na—Si—Ca—B glass has a large viscosity at a high temperature(1 273 K)．For Na．B．Si glass，with the denucleating mechanism similar to Na—Si．Ca．B glass。large degree of undercooling up to 325 K can be obtained for Fe72~Ga275 alloy during the superheating-cooling cycles，and gallium IOSS can be effectively avoided．as Na—B—Si glass has a modest viscosity at a high