BCE催化剂制备高密度聚乙烯管材料-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第5期 PETROCHEMICAL TECHN0LOGY ·547· BCE催化剂制备高密度聚乙烯管材料 孙怡菁，周俊领，郭子芳，马 东 (中国石化 北京化工研究院，北京 100013) [摘要]采用分光光度法、滴定法、粒度分布仪和”C NMR等方法研究了BCE催化剂与国外同类催化剂(Cat A)的组成、粒 径分布、聚合物细粉含量及共聚性能等。实验结果表明，BCE催化剂的细粉含量低且粒径分布集中，制得的聚合物细粉含量 低；BCE催化剂的共聚性能优于CatA催化剂。采用BCE催化剂生产聚乙烯管材料时，母液中的低分子固含量较使用CatA催化 剂时平均减少ll％(w)。BCE催化剂制得的聚乙烯管材料耐慢速裂纹扩展(缺口管)性能超国家标准，耐静液压破坏性能良好。 [关键词]BCE催化剂；聚乙烯；淤浆聚合；管材料 [文章编号]1000—8144(2013)05—0547—04 [中图分类号]TQ 325．12 [文献标志码]A Application of BCE Catalyst in Preparation of High Density Polyethylene Pipe Resins Sun Yijing，ZhouJunling，Guo Zifang，MaDong (SINOPEC Beijing Research Institute ofChemical Industry，Beijing 100013 China) [Abstract]The compositions，particle size distributions and copolymerization performances of BCE catalyst and a commercial catalyst(Cat A)，and the fines content in the polymers prepared with the two catalysts were investigated by means of spectrophotometry，titration，particle size distribution meter and¨C NMR． The results show that BCE catalyst has the features of less fines content，narrower particle size distribution and better copolymerization performance，and the polymer prepared with BCE contains less fines．As for the preparation of HDPE pipe resin with BCE catalyst，the solid content in the mother liquid is averagely reduced by 1 1％(w)compared to Cat A catalyst．The PE pipe resin prepared with BCE catalyst possesses slow crack growth resistance，which can meet the national standard，and good hydrostatic pressure resistance． [Keyword]BCE catalyst；polyethylene；slurry polymerization；pipe resin 聚乙烯(PE)