BCM催化剂催化乙烯-丙烯共聚行为的研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第10期 PETR0CHEMICAL ereCHNOLOGY ·1177· BCM催化剂催化乙烯一丙烯共聚行为的研究 张玉阳，于鲁强，谭 宁，杜亚锋 (中国石化 北京化工研究院，北京 100013) [摘要]采用BCM催化剂催化乙烯一丙烯气相共聚，研究了不同外给电子体及反应条件对共聚反应速率的影响，引入半衰期 概念评价了共聚反应的衰减情况。实验结果表明，通过测定聚合稳定后反应釜内的乙烯与丙烯的摩尔比即可快速判断不同 催化体系中乙烯和丙烯聚合速率的差异。外给电子体对r ／ ( ：乙烯竟聚率；r ：丙烯竟聚率)的影响从大到小的顺序为： 四乙氧基硅烷(T—donor)--异丁基二甲氧基硅烷(B—donor)--异丙基二甲氧基硅烷(P—donor)甲基环己基二甲氧基硅烷 (c—donor)二环戊基二甲氧基硅烷(D—donor)。共聚反应衰减速率的大小顺序为：B—donorT-donorC—donorD—donorP— donor。采用C—donor时，适宜的反应温度为80℃，随反应压力的增大，乙烯的竟聚率增大。 [关键词]BCM催化剂；乙烯一丙烯气相共聚合；竞聚率 [文章编号]1000—8144(2015)10—1177—05 [中图分类号]TQ426．94 [文献标志码]A Gas—Phase Copolymerization of Propylene／Ethylene Catalyzed by BCM Catalyst Zhang Yuyang，Yu Luqiang，Tan Ntng，Du Yafeng (SINOPEC Beijing Research Institute ofChemical Industry，Beijing 100013，China) [Abstract]The gas—phase copolymerization of ethylene and propylene with the BCM catalyst was studied．The effects of different external electron donors and reaction conditions on the copolymerization reaction rate were investigated，and the decay of the copolymerization reaction were evaluated with the half-life(difference between the time when the copolymerization rate reached half of the maximum and the time when the copol~ merization rate reached the maximum)．The results indicated that the copolymerization rate with different catalyst systems could quickly be determined by measuring the ratio of ethylene／propylene in the reaction kettle．The sequence of the effects of the electron donors on rl／r2(rl：reactivity ratio of ethylene；r2：reactivity ratio of propylene)was：