Cr（Ⅲ）微胶囊的制备及其缓释性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 1378· PETROCHEMICAL TECHNOLOGY 2013年第42卷第12期 Cr(Ⅲ)微胶囊的制备及其缓释性能 陈星光，代加林，周 明，胡 成 (西南石油大学 材料科学与工程学院，四川 成都 610500) [摘要]以三氯化铬为芯材、聚丙烯酰胺为壁材，利用反相悬浮聚合和溶剂蒸发法制备了缓释型Cr(Ⅲ)微胶囊，对cr(Ⅲ)微 胶囊的粒径分布进行了测定，并在模拟环境下对Cr(Ⅲ)微胶囊的缓释性能和成胶性能进行了评价。实验结果表明，经1，2， 3次包裹的cr(Ⅲ)微胶囊的粒径分布主要集中在500～700 gm，最大释放率为78％；Cr(Ⅲ)交联剂经包裹后具有明显的缓释效 果，与包裹前相比，部分水解聚丙烯酰胺溶液体系的成胶时间明显延长，可由包裹前的2O h延长至50 h；可以通过控制包裹次 数和合成聚丙烯酰胺壁材所用交联剂的用量来调节成胶时间。 [关键词]溶剂蒸发法；微胶囊；延迟交联；缓释性能；成胶性能；三氯化铬；聚丙烯酰胺 [文章编号]1000—8144(2013)12—1378—05 [中图分类号]TQ 326．4 [文献标志码]A Preparation and Controlled Release Property of Cr(Ⅲ)Microcapsules ChertXingguang，DaiJialin，Zhou Ming，Hu Cheng (Material ScienceEngineering College，Southwest Petroleum University，Chengdu Sichuan 610500，China) l Abstract j Controlled release microcapsules，which could be used in heightening the efficiency of tertiary oil recovery，with chromium trichloride(Cr(Ⅲ)as the core material and polyacrylamide as the wall material were prepared by inverse suspension polymerization and solvent evaporation．The particle size distribution of the microcapsules was determined．The controlled release property and the gelation property of the microcapsules were investigated in a simulation environment．According to the particle size tests of the microcapsules，Cr(IU)release curve in water and Cr(III)／HPAM(partially hydrolyzed polyacrylamide)apparent viscosity curve，it was found that the microcapsule particle size was mainly in the range of 500—700 gm，the maximum release rate was 78％，and the gelation time was enlarged