Cu／ZnO／Al2O3催化剂上仲丁醇脱氢反应动力学研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第1期 PETROCHEMICAL TECHNOL0GY ·49· Cu／ZnO／AI2 O3催化剂上仲丁醇脱氢反应 动力学研究 房德仁，姜雪梅，王知园，邱昭鹏，张慧敏 (烟台大学 应用催化研究所，山东 烟台264005) [摘要]采用管式连续流动固定床反应器，对仲丁醇在Cu／ZnO／A1 O 催化剂上的脱氢反应本征动力学进行了研究，通过双曲线 动力学模型和幂函数动力学模型两种模型计算了该反应的各项参数以及反应的表观活化能，将实验数据用SPSS统计分析软件对 动力学模型进行非线性最小二乘法参数拟合，确定了反应机理并求出了表观活化能。实验结果表明，采用双曲线动力学模型时， 仲丁醇在催化剂表面的脱氢反应为速率控制步骤，表观活化能为64．75 kJ／mol；采用幂函数动力学模型时表观活化能为81．89 kJ／ mol。用相关指数 和F分布对两个速率方程进行了检验，两个速率方程的R 均接近于1，FIOF ，且用双曲线动力学模型时结 果的相关度较高。 [关键词]仲丁醇；脱氢；甲乙酮；动力学；铜／氧化锌／氧化铝催化剂 [文章编号]1000—8144(2011)01—0049—06 [中图分类号]TQ 031．4 [文献标识码]A Kinetics of DehydrOgenati0n of 2-Butanol on Cu／ZnO／Al2 O3 Catalyst Fang Deren，Jiang Xuemei，Wang Zhiyuan，Qiu Zhaopeng，Zhang Huimin (Institute of Applied Catalysis of Yantai University，Yantai Shangdong 264005，China) [Abstract]Reaction kinetics for 2-butanol dehydrogenation on Cu／ZnO／A12 O3 catalyst was studied in a continuous flow fixed—bed reactor．The kinetics parameter fitting was carried out with the nonlinear least square method by means of SPSS statistical analysis software．The reaction mechanism was described by means of Langmuir—Hinshelwood mechanism and empirical mode1．The model parameters and the apparent activation energy of the dehydrogenation reaction were calculated．The results showed that 2-butanol dehydrogenation on the catalyst surface was the rate controlling step in the case of Langmuir—Hinshelwood mechanism as the reaction kinetics model and the apparent activation energy was 64．75 kJ／mo1．But the apparent activation energy was 81．89 kJ／mol in the case of the