介孔分子筛负载茂金属催化乙烯聚合的研究进展-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · l336· PETROCHEMICAL TECHNOLOGY 2014年第43卷第11期 介孑L分子筛负载茂金属催化乙烯聚合的研究进展 党新茹，宫向英，邵三多，郭恩义，韩 冬 (中国石油 大庆石化分公司 塑料厂，黑龙江 大庆 163714) [摘要]介绍了几种常见介孔分子筛(FAU、MFI、M41S系列和sBA系列)，综述了介孔分子筛负载茂金属催化乙烯聚合的研 究进展，重点分析了介孑L分子筛化学组成及孔道结构对负载茂金属催化剂活性及聚合产物的影响，对比分析了介孑L分子筛与 其他几种常见无机载体(硅胶、氯化镁和黏土)的优缺点。介孔分子筛不仅承载了茂金属活性中心，改善了其分散性，而且其 特殊的纳米孔道结构对乙烯单体的扩散有一定的限制作用，导致聚合产物相对分子质量及其分布、形态发生变化。 [关键词]介孔分子筛；茂金属催化剂；乙烯聚合；聚合物形态 [文章编号]1000—8144(2014)I1—1336—07 [中图分类号]TQ 325．1 [文献标志码]A Progresses in Ethylene Polymerization Catalyzed by Mesoporous Molecular Sieve Supported Metallocenes DangXinru，GongXiangying，ShaoSanduo，GuoEnyi，HanDong (CNPC，Plastic Factory ofDaqing Petrochemical，Daqing Heilongdiang 163714，China) l Abstract J Several mesoporous molecular sieves(FAU，MFI，M4 1 S and SBA)in common use were introduced，and the progresses in the ethylene polymerization with the mesoporous molecular sieve supported metallocene catalysts were reviewed．The effects of the chemical composition and pore structures of the mesoporous molecular sieves on the catalyst activities and product properties were discussed．The differences between the mesoporous molecular sieves and other commonly used catalyst supports(i．e．SiO2，MgC12 and clay)were analyzed．In the polymerization process，the mesoporous molecular sieves load the metallocene active sites and change their dispersity，and their specific nano． pores restrict the monomer ethylene diffusion，which results in that the relative molecular mass of the product polyethylene，the relative molecular mass distribution and the product morphology change with