活性组分负载量对顺酐催化剂性能的影响-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第4期 PETR0CHEMICAL TECHN0L0GY ·401· 活性组分负载量对顺酐催化剂性能的影响 陈雅萍，贾雪飞，师慧敏，张东顺 (中国石化 北京化工研究院，北京 100013) [摘要]采用高温涂覆法将活性组分溶液喷涂到惰性载体上制得苯氧化制顺酐的V—Mo催化剂，采用120 mL固定床反应器对催 化剂性能进行评价，通过比表面积测试、XRD和TPD等方法对V—Mo催化剂进行表征。考察活性组分负载量对v—Mo催化剂 性能的影响。实验结果表明，活性组分喷涂负载量(W)在10％～20％时，V—Mo催化剂的活性最好，苯的转化率在98％以上， 顺酐的选择性和收率分别为70％ 80％，69％～80％；随活性组分负载量的增大，V—Mo催化剂的比表面积增大(18．72～28．91 m ／g)，酸量先增加后降低；催化剂的活性组分形成活性固溶体V 。 V芸Moo 。 [关键词]苯氧化；顺酐；钒一钼催化剂 [文章编号]1000—8144(2014)04—0401—04 [中图分类号]TQ 245．23 [文献标志码]A Effects of Active Component Loadings on Catalysts Performances for Oxidation of Benzene to Maleic Anhydride Chen Yaping，JiaXuefei，ShiHuimin，ZhangDongshun (SINOPEC Beijing Research Institute ofChemical Industry，Beijing 100013，China) l Abstract]V-Mo catalysts were prepared by spraying the active components onto an inert support at high temperature．The catalysts were characterized by means of specific surface area analysis，X—ray diffraction and in--situ adsorption·-desorption and their performances in the oxidation of benzene to maleic anhydride were studied in a 1 20 mL fixed—bed reactor．The influences of the active component loading on the catalyst performances were investigated．The experimental results showed that， the catalyst with the active component loading of 1 0％一20％ had the best catalytic performances， the conversion of benzene，the yield of maleic anhydride and the selectivity to it reached more than 98％，70％-80％ and 69％一80％，respectively．With increasing the active component