炼油厂循环冷却水水质稳定剂WSW-216的研制.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第9期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·1677· 炼油厂循环冷却水水质稳定剂WSW-216的研制 陈际帆，周少奇 (华南理工大学环境科学与工程学院，广东 广州 510006) 摘 要：针对炼油厂循环水浊度高，高硬、高碱且含油、浓缩倍数低的特点，以丙烯酸／丙烯酸酯 磺酸盐三元共聚 物、马来酸酐／丙烯酸共聚物、磷羧酸盐和有机膦酸II为阻垢剂，PAPE(多元醇磷酸脂)、有机膦酸II和锌盐为缓 蚀剂，复配出WSW-216型水质稳定剂。动态模拟中间试验结果表明，用该药剂处理k值为 (5．0±o．5)、pH值为 7．0～8．0的水体时，各项指标均达到了循环水质的标准要求，其缓蚀阻垢性能优异。 关键词：循环冷却水；水质稳定剂；阻垢剂；缓蚀剂 中图分类号：TB 495 文献标识码：A 文章编号：1000—6613(2009)09—1677—04 Preparation of water stabilizer WSW-216 of recirculating cooling water in the oil refinery CHENJifan，ZHOU Shaoqi (College ofEnvironmental Science and Engineering，South China University ofTechnology，Guangzhou 510006， Guangdong，China) Abstract：1]he circulatingwaterin oil refineryhasthe characteristics ofhi曲turbidity，highhardness，high alkalinity，bearing oil and low concentrating rate．Aiming at this point，a WSW一216 water stabilizer is compounded by using acrylic acid-acrylate—sulfonate terpolymer，maleic anhydride—acrylic acid copolymer， carboxylate phosphate and organophosphate II as the scale inhibitor， and using polyol phosphate lipid， organophosphate II and zinc salts as the corrosion inhibitor．Dynamic simulation of pilot tests showed that the treatment of recirculating cooling water with concentrating rate of (5．0-x-0．5) and pH 7．o一 ．0 by using WSW一216 as the water stabilizer，all the indexes of the treated water can meet the circulating water quality standard．nlecompoundedWSW 216water stabilizerhasexcenente珩ciencyincorrosionand scaleinhibitions． Kev words：