煤气化耦合C_1合成反应热力学分析-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第12期 PETR0CHEMICAL TECHN0L0GY ·1275· o e e 0 e 0 脚 5研究与开发l 气 ／ 煤气化耦合C1合成反应热力学分析 徐 静，蔡东方，王梓召，王 黎，冯 霄 (西安交通大学 能动学院 多相流国家重点实验室，陕西 西安 710049) [摘要]提出了“煤气化与C。合成叠加耦合”的新工艺思想，即在煤气化过程中，使新生态的H 和CO在具有丰富孔隙结构的煤 表面直接进行C 合成，并对这一新工艺进行了热力学分析。通过化学平衡的热力学分析发现，反应体系的独立反应数为9；生成 各种烃的反应的吉布斯自由能变随温度变化的曲线斜率均为负值，升高温度有利于生成碳原子数多的烃，降低温度有利于生成碳 原子数少的烃；平衡组成中C：～ 烃的含量在900 K左右出现最大值；压力在一定范围内对平衡组成的影响比较明显，适当升高压 力可提高烃的含量；增大n(H2O)：n(C)不利于烯烃的生成。 [关键词]煤气化；C 化学；耦合反应；热力学分析 [文章编号]1000—8144(2011)12—1275—06 [中图分类号]TQ 530．2 [文献标识码]A Thermodynamic Analysis of Coal Gasification Coupling C1 Synthesis Xu Jing，Cai Dongfang，Wang Zizhao，Wang Li，Feng Xiao (State Key Laboratory of Multiphase Flow，School of Energy and Power Engineering，Xi’an Jiaotong University Xi’an Shaanxi 710049，China) [Abstract]A new process for the overlapped coupling between coal gasification and C1 synthesis was proposed，which was in the coal gasification process，hydrocarbons were synthesized from the newly generated carbon monoxide and hydrogen on the coal surface with porous structure． The thermodynamic analysis showed that there were nine independent reactions in the reaction system． Parameters of the independent reactions were obtained by atom matrix analysis．All the curve slopes of Gibbs free energy changes of the reactions with temperature were negative．The temperature rise was beneficial to synthesis of the hydroca