煤焦油分离与精制的研究进展-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 848· PETROCHEMICAL TECHN0L0GY 2014年第43卷第7期 煤焦油分离与精制的研究进展 李艳红 ，赵文波 ，夏举佩 ，刘庆新 ，杨 荣 ，李国斌 (1．昆明理工大学 化学工程学院，云南 昆明 650500； 2．云南云维集团大为制焦有限公司 焦油分厂，云南 曲靖 655338) [摘要]综述了煤焦油分离与精制的研究进展。重点介绍了煤焦油脱水速率模型及蒸馏，酚类、盐基化合物和洗油的分离与 精制，工业萘及精萘的生产，蒽油制取优质新型沥青，煤焦油加氢的研究进展和工艺现状，并对各种分离工艺进行了分析与 比较。还介绍了近年出现的新型煤焦油分离技术，如粗酚加压分解工艺和溶剂提纯工业萘。对煤焦油分离与精制的研究及发 展方向进行了分析和展望，指出萃取和膜分离是盐基化合物提取的发展方向，蒽油制取优质新型沥青是国外研究热点，煤焦 油加氢是提高煤焦油附加值的重要方法。 [关键词]煤焦油；分离；精制；萘；蒽油；沥青 [文章编号]1000—8144(2014)07—0848—08 [中图分类号]TQ 522．6 [文献标志码]A Progresses in the Separation and Purification of Coal Tar Li Yanhong ，Zhao Wenbo ，XiaJupei ，Liu Qingxin ，YangRong ，Li Guobin (1．FacultyofChemicalEngineering，KunmingUniversityofScience andTechnology，KunmingYunnan 650500，China 2．YunnanYunweiGroupDaweiCokingCo．Ltd．CoalTarBranchPlant，QujingYunnan 655338，China) [Abstract]Progresses in the separation and purification of coal tar were reviewed．Rate models for dewatering of the coal tar and the distillation，separation and purification of phenols，nitrogen heterocyclic compounds and absorber oil，production of industrial naphthalene and fine naphthalene， preparation of pitch from anthracene oil，and hydrogenation of the coal tar were discussed．Some novel technologies，namely solvent extraction of industrial naphthalene etc．，were introduced． Solvent extraction and membrane permeation separation were considered to be promising technologies for the production of the nitrogen compounds．The preparation of high—grade pitch from anthracene oil was research hotspot abroad．The hydrotreating of the coal