熔融酯交换法合成聚碳酸酯预聚体-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 76· PETROCHEMICAL TECHlN0L0GY 2012年第41卷第1期 材 料 熔融酯交换法合成聚碳酸酯预聚体 杨孔波，周静宜，陈 放 (北京服装学院材料学院，北京100029) [摘要]采用正交实验研究了以碳酸二苯酯(DPC)和双酚A(BPA)为原料、熔融酯交换法制备聚碳酸酯(Pc)预聚体的合成T 艺；考察了原料配比、出料温度、反应时间、催化剂种类及其用量等因素对PC预聚体的相对分子质量和透光率的影响。实验结 果表明，以乙酸锂为催化剂，在原料配比”(DPC)：月(BPA)=1．04：1、出料温度270 oC、反应时间105 min、催化剂用量0．100％ (基于BPA的质量)的条件下，合成的Pc预聚体的黏均相对分子质量最大。催化剂用量越大，Pc预聚体的黏均相对分子质量越 大；而催化剂用量越少，PC预聚体的透光率越高。 [关键词]碳酸二苯酯；双酚A；熔融酯交换；聚碳酸酯预聚体 [文章编号]1000—8144(2012)叭一0076—06 [中图分类号]TQ 323．41 [文献标识码]A Synthesis of Polycarbonate Precursors Through Melt Transesterification Process Kongbo，ZhouJingyi，ChenFang (Department ofMaterial Science andEngineering，BeijingInstitute ofFashionTechnology，Beijing100029，China) l Abstract j Polycarbonate(PC)precursors were synthesized from diphenyl carbonate(DPC) and bisphenol A(BPA)by melt transesterification．The effects of (DPC)：，z(BPA)，discharging temperature，reaction time，catalyst type and catalyst dosage on the viscosity-average relative molecular mass and the light transmittance of the synthesized PC precursors were investigated by using orthogonal experimental design．The results showed that the viscosity-average relative molecular mass of PC precursors was the highest under the conditions of胛(DPC)： (BPA)1．04：1，discharge temperature 270 ．reaction time 1 05 min and LiAc as the catalyst with dosage of 0．1 00％(based on BPA mass)．With increase of the catalyst dosage，the viscosity—average relative molecular mass of PC precursors increased but the light transmittance decreased．