环氧改性酚醛树脂的合成与研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 PETROCHEMICAL TECHN0L0GY ·583· 2012年第41卷第5期 材 料 环氧改性酚醛树脂的合成与研究 杜 郢，周太炎，王 哲，任筱芳，蔡晓燕 (常州大学 石油化丁学院，江苏 常州 213164) [摘要]合成了酚醛树脂胶黏剂，并采用环氧树脂和有机硅对其进行改性，考察了环氧树脂的加入阶段、种类和加入量及有 机硅加入量对酚醛树脂胶黏剂性能的影响；采用TG．DSC和FTIR等方法对试样进行了表征。实验结果表明，在回流前加人约 1．5％(w)(基于体系质量)的双酚A型环氧树脂E51和约0．6％(W)(基于体系质量)的羟丙基聚二甲基硅氧烷(有机硅8427)，所 得酚醛树脂胶黏剂的黏度适中、柔韧性较好，游离甲醛含量为0．037％(w)，拉伸剪切强度达：~117．1 MPa，各项指标均超过国 家标准；改性后的酚醛树脂胶黏剂的耐热性和柔韧性较改性前均有明显提高。 [关键词]酚醛树脂胶黏剂；环氧树脂；有机硅 [文章编号]1000—8144(2012)05—0583—05 [中图分类号]TQ 322．4 [文献标识码]A Synthesis of Phenol-Formaldehyde Resin Modified with Epoxy Resin Du Ying，Zhou Taiyan，WangZhe，RenXiaofang，CaiXiaoyan (College ofPetrochemical Engineering，Changzhou University，Changzhou Jiangsu 213164，China) [Abstract]A phenol-formaldehyde resin adhesive was synthetized and modified with epoxy resin and organo—silicon．The effects of adding stage，species and dosage of epoxy resin and organo—silicon dosage on the properties of the phenol-formaldehyde resin adhesives were studied．The products were characterized by means of FTIR and TG-DSC．The results showed that the pheno1 formaldehyde resin adhesive modified with about 1．5％(w)(based on the mass of system)bisphenolA epoxy resin(E51)and about 0．6％(w)(based on the mass of system)hydroxypropyl polydimethylsiloxane(organo-silicon 8427)before reflux had modest viscosity and good flexibility．with 0．037％(w)formaldehyde and 7．1 MPa tensile shear strength．The flexibility and thermal resistance ofthe modified phenol-formaldehyde resin adhesive are better than those ofunmodified one． [Keywords J phenol—formaldehyde resin adhesive；epoxy resin；organo—silicon 纯酚醛树脂胶黏剂胶膜性脆、易碎，低交联