萃取精馏分离甲基环己烷和甲苯工艺过程的模拟-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 532· PETR0CHEMICAL TECHN0LOGY 2011年第40卷第5期 萃取精馏分离甲基环己烷和甲苯工艺过程的模拟 张春勇，郑纯智，唐江宏，张国华，单万建 (江苏技术师范学院江苏省贵金属深加工技术及应用重点建设实验室，江苏常州213001) [摘要]利用Aspen Plus流程模拟软件，采用双塔流程，以苯酚为萃取剂，对萃取精馏分离甲基环己烷(MC)和甲苯(MB)的过程 进行模拟计算，并用实验验证。考察了萃取精馏塔的萃取剂进料位置、原料进料位置、萃取剂与原料的摩尔比(溶剂比)和回流比 等因素对分离效果的影响。在满足MC产品的纯度和收率均达到99％的条件下，模拟优化的结果为：理论塔板数为24块，原料在 第17块板进料，萃取剂在第5块板进料，溶剂比3．08，回流比5。模拟结果与实验数据吻合较好，说明采用的模拟方法适用于MC 和MB混合物萃取精馏过程的模拟。 [关键词]Aspen Plus软件；模拟；萃取精馏；甲基环己烷；甲苯 [文章编号]1000—8144(2011)05—0532—04 [中图分类号]TQ 028．1 [文献标识码]A Process Simulation of Extractive Distillation for Methylcyclohexane and Toluene System Zhang Chunyong，Zheng Chunzhi，Tang Jianghong，Zhang Guohua，Shan Wanjian (Jiangsu Key Laboratory of Precious Metal Chemistry and Technology， Jiangsu Teachers University of Technology，Changzhou Jiangsu 21 3001，China) [Abstract] Extractive distillation process for methylcyclohexane(Mc)and toluene(MB)system was simulated by using Aspen Plus software．Phenol was chosen as the extractant．A process with two columns，namely extractive distillation column and solvent recovery column ，was designed for separating the mixture．Effects of the extractant feed position and the mixture feed position on the extractive distillation column，the mole ratio of extractant to feedstock(solvent ratio)，and the reflUX ratio on the extractive distillation were investigated．Aimed at the MC mole fraction of 99％ in the products and the MC recovery of 99％ ．the extractive distillation process was simulated to obtain the optimal conditions f