裂解汽油加氢钯系催化剂中毒原因的分析-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 1076· PETROCHEMICAL TECHNoLoGY 2014年第43卷第9期 裂解汽油加氢钯系催化剂中毒原因的分析 薛慧峰，耿占杰，王 芳，秦 鹏，马好文，范国宁 (中国石油 石油化工研究院 兰州化工研究中心，甘肃 兰州 730060) [摘要]对某石化公司裂解汽油加氢装置的钯系催化剂在使用过程中出现的中毒失活问题进行了分析研究。比较了中毒催化 剂与新鲜催化剂的晶相和钯含量，并分析了原料中砷、水和硫化物的含量及硫化物的分布。分析结果表明，中毒前后催化剂 的晶相和钯含量没有明显变化，原料中砷、水和硫化物的含量在正常范围内，但原料eecs：含量较高，达N I．8～2O．2 ktg／g。分析 了生产正常的裂解汽油加氢原料，原料中cs：的含量低于1 ktg／g。CS：、二甲基二硫醚和噻吩的致毒性评价实验结果表明，致 毒性大小的顺序为：CS 二甲基二硫醚噻吩。由此确定了导致钯系催化剂中毒的物质是cs：。一段加氢原料中cs 含量与C 含 量基本呈线性关系，将一段加氢原料中c 含量控制在0．5％(W)以下，cs：含量会降至1 g以下，使加氢生产保持正常。 [关键词]裂解汽油；钯系加氢催化剂；催化剂中毒；二硫化碳 [文章编号]1000—8144(2014)09—1076—06 [中图分类号]TQ426，8 [文献标志码]A Cause ofPoisoning ofPalladium-Based Catalystfor Hydrogenation ofPyrolysis Gasoline XueHuifeng．GengZhanjie．WangFang，Qin Peng，MaHaowen，Fan Guoning (Lanzhou Center ofPetrochemical Research Institute，Petrochina，Lanzhou Gansu 730060，Chma) [Abstract]The deactivation of palladium-based catalyst for the hydrogenation of pyrolysis gasoline was investigated．The crystallite structure and palladium content of the poisoned and flesh catalyst were measured．The contents of arsenic，H2O and sulfides in the feedstocks were determined．The results showed that the crystallite structure and palladium content of the catalyst almost unchanged after poisoning．The contents of arsenic，H2O and sulfides in the feedstocks were within normal limits， but the content of CS2 in the feedstocks was high in the range of 1．8-20．2 gg／g．The CS2 content in feedstock should be less than l g in well—running hydrogenation units．A deactivation test for the hydrogenation catalyst was carried out by adding CS2， dimethyl d