高效乙烯淤浆聚合催化剂的制备及其性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · l344- PETR0CHEMICAL TECHN0LOGY 2010年第39卷第l2期 ．_．_I— Cj 同 效乙烯淤浆聚合催化剂的制备及其性能 崔楠楠，周俊领 (中国石油化工股份有限公司 北京化工研究院，北京 100013) [摘要]制备了一种高效乙烯淤浆聚合催化剂MgCI2一TiCI4一Ti(OEt)4；考察了制备条件对该催化剂性能的影响，并与商品催化 剂(BCH)对比了催化剂的粒径分布和聚合物的颗粒形态；考察r MgC1 一TiC1 一Ti(OEt) 催化乙烯均聚及乙烯与】一己烯共聚 的性能。研究结果表明，载钛温度对MgC12一TiCI4一Ti(OEt)4催化剂性能的影响至关重要；MgC12一TiC14一Ti(OEt)4催化剂的 颗粒形态优于BCH催化剂，聚乙烯中的细粉含量显著降低，聚乙烯的粒径分布更集中；共聚单体l一己烯的加入使共聚物的密度 和熔点同时降低，共聚物中的细粉含量低于BCH催化剂制备的共聚物；H，的加入提高了聚乙烯的熔体流动指数，降低了聚乙烯 的熔点，增加了聚乙烯的结晶焓。 [关键词]乙烯聚合催化剂；淤浆工艺；聚乙烯；1一己烯 f文章编号]1000—8144(2010)12—1344—05 [中图分类号]TQ 3l6 [文献标识码]A Preparation and Performance of Polyethylene Catalyst for Slurry Process Cui Nannan，Zhou Junling (Beijing Research Institute ofChemical Industry，SINOPEC，Beijing 100013，China) [Abstract] A ethylene polymerization catalyst MgC12-TiC14-Ti(OEt)4 for the slurry process was prepared．Effects of the reaction conditions on performance of the catalyst were studied．Compared with the commercial BCH catalyst，particle size distributions of both the prepared catalyst and the polymers，and the performances of the catalyst in both ethylene homo—polymerization and ethylene copolymerization with，z—hexene were discussed．The results indicated that the temperature of loading Ti obviously affected the performance of the catalyst．Morphology of the catalyst MgC12-TiC14-Ti(OEt)4 was better than that of the BCH catalyst，the fine powder content in the product polyethy