溶解性有机质对Cu在土壤中吸附-解吸行为的影响.pdfVIP

农业环境科学学报 2oo8.27(5): 1779-1785 JoumalofA伊O-Enviromnent Scien伺 溶解性有机质对 Cu 在土壤中吸附…解吸行为的影晌 祝亮川，伍钧1 ，周江敏2，陈华林2 ，唐东民 1 ， 2 (1.四川农业大学资源环境学腕，四川雅资 625014;2. 温州大学生命与环境科学学陇，浙、江温州 3250盯) 摘 票:通过商内实验研究了水稻秸轩不同腐解阶段产生的辩解性有机质(DOM)对Cu 在黄筋泥(水稻土)中吸附m解吸行为的影 响。结果表明.Freundlich 方和能很好地描述Cu 在土壤中的吸附解吸行为。加入Od-DOM 能增大吸附和解吸体系中的pH 值，明显 降低 Cu 在土壤中的迟滞系数，抑制 Cu 在黄筋泥(水稻士)上的吸附、促进其解吸，且与对照和其他几个阶段 DOM 的影响存在极显 著差异(PO.Ol)。加入其他腐解阶段的 DOM 也能增大吸附和解吸体系中的 pH。在 Cu 浓度较低时降低迟滞系数，抑制吸附，促进解 吸;高浓度时增加迟滞系数，促进吸附，抑制解吸。 关键询:溶解性有机质;制;吸附;解吸;迟滞 中阻分类号:X13 1.3 文献标识码:A 文章编号: 1672-2043(2∞8)05由1779-07 EtTect of Dissolved Organic Matter 00 SOrp创oo-I沁so叩创00 Behavior of Copper io Soil l l 2 2 l ZHU Liang .2, WU Jun ,ZHOU Jiang-min ,CHEN Hua-lin ,TANG Dong-min .2 (1. College of Re80urce曲 and Environment. Síchuan A萨icultural Univef!lity , Ya an 625014, China; 2. School of Lífe and Enviromnental Sci叩 enc棚， Wenzhou Univef!lity ,Wenzhou 325027,China) Abs衍act: 叽le impact of dis80lved organic matter derived from difIerent decomposition stage of crop straw on theωIrption-de80rptíon behav.… ior of 80il copper (Cu) was studied.ηle results showed that Freundlich model could completely explain the mechanism of the 回il Cu 回叩tíon and de80rption. 0 day-dissolved organic ma忧er increased the pH of ω，rption-desorption system, si伊tificantly decreased the hysteresis index ofsoil Cu，伊eaÙY reduced the 8Orption capacity of 回il Cu ,and accelerated the de抽甲tion of so诅 Cu. Further,there was significant difIerence (PO.OI) between the 0 day phase of dis80lved 0鸣anic ma饥.er and other phases of dis80lved organic matter. Other decomposition phases of dissolved organic ma忧.er could also increase the pH in 8Orption-de80rption system. Whenωil Cu concentration wωlow， ít decreased the hys- teresis index ofωil Cu ,restrained the 8Orption of 80il Cu , and accelerated the de80rption of 80il Cu, since the chelation effect was better 也m pH effect at 由is time. on the other hand,