助交联剂松香酯对聚丙烯交联性能的研究.pdfVIP

第44 卷第 12 期 塑料工业 1··a··a CHINA PLASI1CS lNDU盯RY . . 2016 年 12 月 助交联剂松香醋对聚丙烯交联性能的研究 柯昌美，杨柯·，陈梅 (武仅科技大学化学工程与技术学院，湖北武仅 43∞81 ) 摘要:以过氧化二异丙苯(DCP) 为主交联剂，松香醋为助交联剂，采用化学交联法对聚丙烯进行交联改性。 分 别测试DCP 和DCPI松香醋交联体系下， PP 的熔体质量流动速率-凝胶含量-抗熔断能力以及力学性能。 结果表明， 与单独使用 DCP 相比， DCPI松香酶交联体系使PP 抗熔断能力延长了 12 min，当 DCP 为2 phr 时， PP 的熔体质量流动 速率减少了o. 1 gllOmin，凝胶含量提高了 15% ，冲击强度和拉伸强度分别增加了0.73 kJ/m2 1. 97 MPa。 、 关键词:聚丙烯;交联;改性;熔体强度 doi: 10. 3969/j. issn. 1∞5-5770.2016.12.026 中图分类号: TQ325 . 1+4 文献标识码:A 文章编号: 1ω5-5770 (2016) 12-0111-03 Rωearch of the PrOperties of Turpentine-assisted Crωslinked， Polypropylene KE Chang-mei , YANG Ke , CHEN Mei (Sch∞1 of Chemical engineeríng and technology , Wuhan University of Science and Technology , Wuhan 43∞81 ， China) Abs衍act: Polypropylene (PP) resin was cross-linked by chemical crosslinking me由odwi由 dicumyl peroxide ( DCP )脑 the major cross-linking agent and turpentine as the assistant crosslinker. In the absence and presence of turpentine , the melt flow rate , anti-sagging ability , gel content and mechanical properties of polypropylene were measured , respectively. 币le results show that DCP/turpentine crosslinking system prolongs the anti-sagging time of PP by 12 minutes. When adding 2 phr DCP in polypropylene , the maximal gel percentage of the cross-linked PP is improved by 15% , its impact strength is increased by 2. 31 kJ/旷， and its tensile strength increases by 1. 97 MPa , compared wi由 pure PP. Keywords : Polypropylene; Crosslinking; Modification; Melt 5tren