测试分析知识讲座路.pptVIP

科 研 知 识 讲 座 ５－２．红外光谱测试结果－BaTiO3 5 - 3 红外光谱随稀土掺杂量的变化 Fig. 5 Infra-red spectra of the Ba1-xEuxTiO3. Red shift △Te and △Tr represent absorption peak shift to low frequency with increasing Eu content for tetravalent and trivalent Ti-O band stretching vibration respectively. 六．光电子能谱分析 ６－１． Eu 4d XPS 谱 Fig. 6 - 1. Eu 4d XPS patterns for Ba1-xEuxTiO3. The dashed lines with the same ratio of slope are taken as linear background for data analysis of Eu 4d. ６－１． Eu 4d XPS 谱分析 Fig. 6 -1 . Gaussian fitting analysis for Eu 4d XPS spectra of the Ba1-xEuxTiO3 samples. The linear background with the same slope in Fig.1 was subtracted. The percentages determined only by peak intensity denote the content of Eu2+ ions and Eu3+ ions respectively, regardless of surface layer effect in trivalent Eu insulating compounds. ６－３． Ti 2p XPS 谱 Fig. 6 - 2. Ti 2p XPS patterns for the Ba1-xEuxTiO3. (a) Experimental spectra, (b) Ti 2p spectra obtained by subtracting linear background, Ti 2p spectrum of x=0.1 sample is well curve fitted. ６－４． O1s 　XPS 谱 Fig. 6 - 2. Gaussian fitting for O1s peaks of the Ba1-xEuxTiO3. Linear background was subtracted. OL represents lattice oxygen, OA absorbed oxygen. 七．电子顺磁共振谱（ESR） ７－１． FE3X-1型电子顺磁共振仪（ESR信号随温度的变化） 主机控制与记录系统 处于磁场中的样品室 信号监视与校正系统 信号输出与频率控制系统 加热系统 ７－２． JES-FR30T型电子顺磁共振仪 （测量室温的ESR信号） ７－３． 室温ESR谱测量结果 Fig. 7 - 1. ESR spectra at room temperature for (a) BT, (c) BL3T, (d) BTC5, (e) BL3TC5 ceramics, and BL3T powders calcinated at 1100℃ (f), and sintered at 1300℃ (b). ７－４． ESR信号随温度的变化 Fig. 7 - 2. Variation in ESR signals with temperature for highly insulating (a) BL4TC5, (b) BL4T and (c) BT ceramics. 八．拉曼光谱 8-1 拉曼光谱 Fig. ８－１. Depolarized room-temperature Raman spectra (Stokes components) of (a) BT, (c) BL3T, (d) BTC5, (e) BL3TC5 ceramics, and (b) BL3T powder sintered, denoted by C and P in brackets respectively. The inset depicts the variation in FWHM of ~513 cm-1 peak with ionic type doping. * * 测试与分析技术知识讲座 Lecture on the knowledge of measurement and a