GC-MS法快速测定原油中沸点低于540℃馏分的详细烃组成-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第3期 PETR0CHEMICAL TECHN0L0GY ·381· GC—MS法快速测定原油中沸点低于540℃ 馏分的详细烃组成 刘颖荣，刘泽龙，田松柏，蔡新恒 (中国石化 石油化工科学研究院，北京 100083) [摘要]以原油为研究对象，根据Robinson原理，将GC．MS技术与现有各烃类组成测定的ASTM标准方法相结合，在无需对油 样进行前处理的情况下，直接采用GC．MS法分析原油组成，建立了一种快速分析原油中沸点低于540。c馏分的详细烃组成的 方法。对于原油中沸点低于180℃( ．C ，之前)的石脑油组分依据标准方法直接进行定性定量分析；对于沸点在180～540℃ (n．C )的柴油和蜡油馏分，研究了其分离后的纯饱和烃和纯芳烃的断裂质谱图，建立了饱和烃模型适合法和基线法，即将 未分离原油的质谱图分为饱和烃谱图和芳烃谱图，从而实现了不需物理预分离而直接得到饱和烃和芳烃的详细烃组成，其中 包括4类饱和烃、12类芳烃和3类噻吩等详细烃组成，该结果符合相应ASTM标准方法的再现性要求。 [关键词]原油；色谱．质谱法；烃组成；饱和烃；芳烃 [文章编号]1000．8144(2015)03—0381．08 [中图分类号]TE 135．4 [文献标志码]A Rapid Determination ofHydrocarbon Types with Lower Boiling Pointthan 540℃ in Crude Oils by GC-MS Method Liu Yingrong，Liu Zelong，Tian Songbai，CaiXinheng (S1NOPEC Research Institute ofPelxoleum Processing，Beijing 100083，China) [Abstract]A rapid and direct analysis method for the detailed hydrocarbon types with lower boiling point than 540 oC in crude oils was established by the combination of GC-MS with ASTM test standard methods without any pre—treatment to the samples．For naphtha fractions(1ower boiling point than 1 80 oC)with retention time less than that of n-C… the detailed hydrocarbon composition could be analyzed by GC according to ASTM D5 1 34．For the fractions(n-C11_44)with the boiling point range of 1 80—540℃．the mass spectra of separated saturates and aromatics were investigated after the separation，the lOW mass pattem，base—line method and correction factors were presented，and the detailed compositions of 4 saturated hydro