鹏酚醛树脂多壁碳纳米管.pdfVIP

Polymer Degradation and Stability 94 (2009) 1972–1978 Contents lists available at ScienceDirect Polymer Degradation and Stability journal homepage: www.elsevi /locate/polydegstab Effects of modified multi-walled carbon nanotubes on the curing behavior and thermal stability of boron phenolic resin Lin Liu a, b, *, Ziping Ye a a School of Materials Science and Engineering, Tongji University, Shanghai 200092, China b Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Shanghai 200092, China a r t i c l e i n f o a b s t r a c t Article history: One kind of boron phenolic resin (BPR) was prepared from the solvent-less reaction of resoles with boric Received 23 June 2009 acid. X-ray photoelectron spectroscopy (XPS) showed that the reaction degree of boric acid was 83.8%. Received in revised form Multi-walled carbon nanotubes (MWCNTs) were modified by nitric acid, 4,40 -Diaminodiphenyl methane 23 July 2009 and boric acid. The effect of modification was determined by Fourier transform infrared (FT-IR), ther- Accepted 26 July 2009 mogravimetric analysis (TGA) techniques and XPS. The cure kinetics and thermal behavior of BPR and Available online 30 July 2009 modified multi-walled carbon nanotubes (m-MWCNTs)/BPR were studied. It was found that the curing apparent activation energy (Ea) decreased with the increasing amount of m-MWCNTs. But there was no Keywords: Boron