KF／锌铝水滑石的制备及其催化大豆油酯交换反应的性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2016年第45卷第 1期 PETR0CHEMICAL TECHN0LoGY ·47· DOI：10．3969~．issn．i000—8144．2016．O1．008 KF／锌铝水滑石的制备及其催化大豆油 酯交换反应的性能 田志茗，常宝琪，邓启刚 (齐齐哈尔大学 化学与化学工程学院，黑龙江 齐齐哈尔 161006) [摘要]通过浸渍法制备了KF／锌铝水滑石固体碱催化剂，通过XRD、TG—DSC和氮气吸附一脱附等方法对催化剂进行了表 征，考察了催化剂的制备条件，并将其用于催化大豆油与甲醇酯交换制备生物柴油的反应。实验结果表明，KF负载量为85％ (W)、在500℃下焙烧3 h时制备的KF／锌铝水滑石催化剂对大豆油酯交换反应表现出良好的活性，当大豆油与甲醇的摩尔比为 12：1、催化剂用量为3％(相对于大豆油的质量)、在65℃下回流3 hue，大豆油的转化率可达N85．94％。表征结果显示，KF／ 锌铝水滑石催化剂的活性与KF和水滑石在高温煅烧时相互作用形成的新晶相K，A1F 和KOH有关。 [关键词]KF／锌铝水滑石催化剂；酯交换反应；大豆油；甲醇；生物柴油 [文章编号]1000—8144(2016)O1—0047—05 [中图分类号]TQ 426 [文献标志码]A Preparation and catalytic activity of KF／Zn—AI hydrotalcite catalyst for transesterificatiOn of soybean oil Tian Zhiming，ChangBaoqi，Deng Qigang (School ofChemistry andChemicalEngineering，QiqiharUniversity，QiqiharHeilongjiang 161006，China) [Abstract]KF／hydrotalcite solid base catalysts were prepared by impregnation and were characterized by means of XRD，TG．DSC and N，adsorption—desorption．The catalysts were used in the transesterificatiOn of soybean oil and methanol to biodiesel oil and their preparation conditions were investigated．The optimum preparation conditions were KF loading(based on the KF／Zn(A1)O mass) 85％．calcination temperature 500 oC and calcination time 3 h．Under the transestefification conditions of the KF／hydrotalcite catalyst dosage 3％(based on the SOybean oil mass)，n(methano1)：n(soybean oil)1 2：1。reaction temperature 65℃and reaction time in refluxing state 3 h。the conversion of soybean oi1 reached 85．94％．The