MgO改性MCM-22分子筛催化苯与碳酸二乙酯的烷基化反应-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2010年第39卷第4期 PETR0CHEMICAL TBCHN0LOGY ·391· MgO改性MCM一22分子筛催化 苯与碳酸二乙酯的烷基化反应 李永昕，马 壮，薛 冰 (江苏工业学院 化学化工学院，江苏 常州 213164) [摘要]以Mg(NO3)2为前体，在MCM一22分子筛上负载不同量的MgO，制备了MgO改性的MCM一22分子筛(MgO／MCM一 22)催化剂；在固定床连续微反装置上，考察了MCM一22分子筛原粉和MgO／MCM一22催化剂对苯与碳酸二乙酯进行烷基化反 应合成乙苯的催化性能；采用XRD、BET、NH3一TPD和吡啶吸附红外光谱等手段对催化剂进行了表征。实验结果表明，随MgO 负载量的增加，苯的转化率逐渐降低，而乙苯的选择性逐渐升高。表征结果显示，随MgO负载量的增加，催化剂的酸强度减弱，酸 量减少；催化剂的比表面积和孔体积也随MgO负载量的增加而减小，从而导致苯的转化率随MgO负载量的增加而逐渐降低；而 减少的酸中心抑制了副反应的发生，因此乙苯的选择性随MgO负载量的增加而增大。适宜的MgO负载量(质量分数)为3％。 [关键词]MCM一22分子筛；氧化镁；苯；碳酸二乙酯；烷基化；乙苯 [文章编号]1000—8144(2010)04—0391—05 [中图分类号]TQ 241．1 [文献标识码]A Alkylation of Benzene with Diethyl Carbonate over MgO—Modified MCM-22 Molecular Sieves Li Yongxin，Ma Zhuang，Xue Bing (Deparmaent ofChemical Engineering，Jiangsu Polytechnic University，Changzhou hangsu 213164，China) [Abstract]MgO—modified MCM-22 molecular sieves(MgO／MCM-22)catalysts with different MgO loadings were prepared through impregnation with Mg(NO3)2 as precursor．Alkylation of diethyl carbonate with benzene was studied over parent MCM-22 molecular sieves and the prepared MgO／ MCM-22 catalysts separately in a continuous flow fixed—bed reactor．The MCM-22 molecular sieves and the catalysts were characterized by means of XRD，BET，NH3-TPD and pyridine—IR． The alkylation results showed that with increasing of MgO loading，conversion of benzene reduced，while selectivity to ethylbenzene rose．The characterization results showed that with increasi