XRD表征氯化镁乙醇醇合物的结构-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 1128· PETROCHEMICAL TECHN0L0GY 2014年第43卷第10期 XRD表征氯化镁乙醇醇合物的结构 岑 为，夏先知，刘月祥，毛炳权 (中国石化 北京化工研究院，北京 100013) [摘要]制备了一系列乙醇与MgC1：摩尔比(简称醇镁比)不同的MgC1：醇合物，采用XRD方法研究TMgC1 醇合物的晶体结 构，并通过对晶胞参数的计算分析TMgCI：醇合物中结构稳定的组分。表征结果显示，醇镁比在1．5～6之间的MgCI：醇合物有4 种结构稳定的组分，分别为MgC126EtOH，MgC123．33EtOH，MgCI22．8EtOH，MgC1 ·1．5EtOH。不同醇镁比的MgC1 醇合物是 由这4种结构稳定的组分中的一种或几种组成的。 [关键词]氯化镁醇合物；丙烯聚合催化剂载体；X射线粉末衍射；脱醇 [文章编号]1000—8144(2014)10—1128—05 [中图分类号]TQ 426．65 [文献标志码]A Characterization of Magnesium Chloride—Ethanol Adduct by X—Ray Powder Diffraction Cen Wei，XiaXianzhi，Liu Yuexiang，Mao Bingquan (S1NOPECBeijingResearchInstituteofChemicalIndustry，Beijing 100013，China) [Abstract]Magnesium chloride—ethanol adducts，which were used as catalyst supports for propylene polymerization，with different molar ratio of EtOH to MgC12( )were prepared and characterized by means of X—ray powder diffraction．The components of the adducts were investigated through the calculation of the unit cell parameters of their crystal structures．It was showed that there were four stable crystal structures in the MgC1，·nEtOH adducts with 1．5≤聆≤6，which were MgC1，· 6EtOH，MgC12‘3．33EtOH，MgC12。2．8Et0H and MgC12。1．5EtOH．In addition，the MgC12‘ EtOH adducts with 1．5≤ ≤6 consisted of one or several of the four adducts． [Keywords]magnesium chloride-ethanol adduct；catalyst support for propylene polymerization； X．ray powder difiraction：dealcoholization MgC1 醇合物是制备高效球形丙烯聚合催化剂 6，4．5，4，3．33，2．5，1．67，1．5，1．25的MgCI2 的常用载体 J。丙烯聚合催化剂是一个复杂的多