三次采油耐温抗盐聚丙烯酰胺的结构与性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 T · 770· PETR0CHEMICAL TECHNOL0GY 2015年第44卷第6期 三次采油耐温抗盐聚丙烯酰胺的结构与性能 伊 卓，刘 希，方 昭，杜 超，黄凤兴 (中国石化 北京化T研究院，北京 100013) [摘要]开发适合的耐温抗盐聚合物驱油剂是高温高盐油藏化学驱提高采收率技术的关键。从高分子物理的角度介绍了聚丙 烯酰胺(HPAM)耐温抗盐性能提升的结构途径，总结比较了不同类型耐温抗盐HPAM的结构特点，分析了HPAM的一级、二 级和三级结构与性能的关系：一级结构为结构单元的化学组成、构造和序列结构，二级结构为链的柔顺性和相对分子质量及 其分布，i级结构为分子间作用力。提出了=i次采油耐温抗盐HPAM的研究方向。 [关键词J三次采油；耐温抗盐；聚阿烯酰胺；驱油剂 [文章编号]1000—8144(2015)06—0770—08 [中图分类号]TE 357．462 [文献标志码]A Structure and Properties of Temperature—Tolerant and Salt-Resistant Polyacrylamide for Tertiary Oil Recovery Zhuo，LiuXi，FangZhao，Du Chao，HuangFengxing (S1NOPECBeijingResearchInstitute ofChemicalIndustry，Beijing 100013，China) l Abstract]The development of suitable temperature—tolerant and salt—resistant oil-displacing agents is a key technology for enhanced oil recovery in tertiary oil recovery．Based on the polymer physics， some approaches for improving the temperature--tolerance and salt-·resistance of polyacrylamide (HPAM)were introduced．Meanwhile，the structural features of different types of HPAM were summarized，especially the relationship between the structures(including chemical composition， construction and sequence of structural units called as the primary structure；flexibility of polymer chains，molecular weight of polymer and its distribution called as the secondary structure； and intermolecular interaction called as the tertiary structure)and properties．Besides，the future development of HPAM with temperature—tolerance and salt-resistance was also predicted． [Keyw