含瓜尔胶的反相乳液稳定性的研究.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第10期 PETR0CHEMICAL TeCHN0L0GY ·1063· 含瓜尔胶的反相乳液稳定性的研究 张贤贤，李友明，万小芳，翁爱玲 (华南理工大学 制浆造纸工程国家重点实验室，广东 广州 510640) [摘要]以液体石蜡为油相，质量分数为2．5％的瓜尔胶水溶液为水相，Span80／OP一10为复配乳化剂，十六醇为助稳定剂，制备了 稳定的反相乳液。考察了Span80／OP一10复配乳化剂的亲水一亲油平衡(HLB)值及其含量、反相乳液中水相含量、十六醇含量 及搅拌转速对乳液类型及其稳定性的影响；并使用显微镜及粒度分析仪对乳液的结构进行了表征。实验结果表明，反相乳液的最 佳制备条件为：Span80／OP一10复配乳化剂的HLB值和质量分数分别为7．36和10％(基于油相的总质量)，十六醇质量分数 3 75％(基于油相的总质量)，水相的体积分数33％，搅拌转速为2 100 r／min。反相乳液中的胶束为球形且呈分散状，平均粒径小 于10 m且分布较窄。 [关键词]瓜尔胶；反相乳液；十六醇；乳液稳定性；液体石蜡 [文章编号]1000—8144(2011)10—1063—05 [中图分类号]TQ 316．334 [文献标识码]A Stability of Inverse Emulsion Containing Guar Gum Zhang Xianxian，Li Youming，Wan Xiaofang，Weng Ailing (State Key Laboratory of PulpPaper Engineering，South China University of Technology，Guangzhou Guangdong 5 10640，China) [Abstract]The inverse emulsions were prepared with liquid paraffine as oil phase，2．5％(W)guar gum aqueous solution as aqueous phase，Span80／OP一10 complex emulsifier and cetanol as co— stabilizer．The effects of hydrophilic—lipophilic balance(HLB)value and the concentration of Span80／ OP一10 complex emulsifier．the volume fraction of the aqueous phase．the concentration of cetanol and stirring speed on the type and stability of the emulsion were investigated．The structure of the emulsion was characterized by means of microscope and granulometer．The results showed that the optimum conditions for preparation of the inverse emulsion were：HLB of 7．36 and 1 0％(W)(based on the total mass of the oil phase)Span80／OP一10 complex emulsifier，3．75％(W)(based on the total mass of the oil phase)cetanol，33％( )the aqueous phase and stirring speed of 2 10