吸附法脱除异戊烷中的3-甲基丁烯.pdfVIP

学兔兔 石 油 化 工 2010年第39卷第2期 P】 TROCHEM1CAL TECHN0L0GY ·l73· 吸附法脱除异戊烷中的3一甲基丁烯 王丹丹，徐 军，孟长功 (大连理工大学 化学系，辽宁 大连 116024) [摘要]采用水溶液离子交换法制备了AgY和AgMOR分子筛吸附剂，在固定床中考察了分子筛吸附剂种类及吸附温度、床层高 度、原料气流量等条件对脱除异戊烷中的3一甲基丁烯效果的影响。实验结果表明，AgY和AgMOR分子筛保持原有的骨架结构； AgY分子筛可作为脱除异戊烷中3一甲基丁烯的吸附剂；在2O oC、0．1 MPa、原料气流量为40 mL／min时，经过两次离子交换的 AgY(2)分子筛吸附剂的饱和吸附量为115 nq eVg；在固定床中，不可利用床层高度(LUB)与原料气流量有关，与床层高度无关，但 只有当床层高度超过LUB时，才有吸附效果；AgY分子筛吸附剂可脱附再生l8次。 [关键词]AgY分子筛吸附剂；离子交换；吸附法；3一甲基丁烯；异戊烷 [文章编号]i000—8144(2010)02—0173—05 [中图分类号]TQ 028．15 [文献标识码]A Purification of Isopentane Containing 3-Methyl-1--Butene Through Adsorption Wang Dandan，Xu Jun，Meng Changgong (Department of Chemistry，Dalian University of Technology，Dalian Liaoning 1 16024，China) [Abstract] Both AgY and AgMOR molecular sieve adsorbents were prepared by ion exchange method in water solution． Removal of 3·methyl一1一butene in isopentane on the prepared AgY or AgMOR molecular sieve adsorbent was investigated in a fixed·bed microreactor．Effects of adsorbent type，adsorption temperature，bed height and feed gas flow rate on the adsorption were studied．Crystal structures of both Y and MOR were maintained after Ag exchange was carried out． The AgY molecular sieve was a good adsorbent for adsorption of 3一methyl一1·butene in isopentane． Under adsorption condition：20℃，0．1／~lPa and feed gas flow rate 40 mL／min，saturated adsorption capacity of the AgY molecular sieve was 1 15 meVg．In the fixed—bed reactor，length of unused bed (LUB)was related with the gas flow rate but not with the bed height．The molecular sieve adsorbents would be effectiv