铁柱撑膨润土与H2O2联合处理酸性大红模拟染料废水.pdfVIP

学兔兔 石 油 化 工 2014年第43卷第1期 PETROCHEMICAL TECHNOLOGY ·101· 铁柱撑膨润土与H2o2联合处理 酸性大红模拟染料废水 曹春艳 ，赵莹莹 ，李 鑫 (1．渤海大学 化学化工与食品安全学院，辽宁 锦州 121013； 2．中国石油管道学院 管道运输系，河北 廊坊 065000) [摘要]以天然膨润土为载体，采用离子交换法制备了铁柱撑膨润土(Fe—Bent)催化剂，并与H：O 组成类芬顿体系，对酸性 大红模拟染料废水进行降解处理；考察了Fe—Bent催化剂用量、H：O 浓度、溶液pH、反应温度和反应时间对酸性大红去除率 的影响，并对Fe—Bent~化剂进行了XRD表征。表征结果显示，Fe—Bent~化剂中铁以c【一Fe，O 的形态存在。实验结果表明，在 Fe—Bent~化剂用量1．0 g、H2O2的浓度6 mmol／L、溶液pH 3．0、反应温度60℃、反应时间80 min的适宜条件下，处理100 mL质 量浓度为20 mgm的酸性大红模拟染料废水，酸性大红的去除率可达94．87％。Fe—Bent~化剂的稳定性较好，循环使用4次后仍 具有较高活性。 [关键词]铁柱撑膨润土；过氧化氢；类芬顿体系；染料废水；酸性大红；废水处理 [文章编号]1000—8144(2014)01—01O1—05 [中图分类号]TQ 610．9 [文献标志码]A Treatment of Simulant Acid Scarlet Dye Wastewater th Fe—Pillared Bentonite and H2O2 Cao Chunyan ，Zhao Yingying ，LiXin (1．College ofChemistry，ChemicalEngineering andFood Safety，BohaiUniversity，JinzhouLiaoning 121013，China 2．Department ofPipeline Transport，China Pipeline Petroleum College，Langfang Hebei 065000，China) l Abstract J An Fe—pillared bentonite(Fe—Bent)catalyst was prepared by ion—exchange method with natural bentonite as the support and a Fenton—like system composed of Fe—Bent and H2O2 was used to treat simulant acid scarlet dye wastewater．The effects of Fe—Bent dosage，H，O々concentration， solution pH，reaction temperature and reaction time on the removal rate of the acid scarlet were investigated．The Fe—Bent catalyst was characterized by means of XRD．which showed the existence of 0【一Fe，O in the Fe—Bent catalyst．The removal rate of the aci