原子荧光光度计测砷检出限测量结果的不确定度的分析.pdfVIP

计量与测试技术 2010 年第37 卷第12 期 56 Analysis f or Measurement Uncertainty of the Instr ument Detection Limit of Atomic Fluorescence Sp ectrometry f or As 蒋孝雄 ( , 210007) : , , , : ; ; ; 1 20 60 22 , ( 1) , Q = 3S / b L ( k = 3) 0 : QL ( k= 3) ! ; S0 ! 11 , , ; b ! , , ( 2) , 2 QL (k = 3) 2 2 QL (k = 3) 2 2 u ( Q ) = ( ) u (s ) + ( ) u ( b) c L (k = 3) S0 0 b QL ( k = 3) = 3 QL ( k = 3) = - 3S20 S0 b b b ( Uncertainty Of Measurement) 23 , , ( 1) , , , ( CNACL) 1 2( 100mL) , 1 11 , 1 2 3 4 5 6 7 8 10 11 2 If 65 52 - 14 - 3 - 14 - 02 - 01 65 52 14 23 , : I = 18; S = 36 21 f O JJG 3 - 200 2 , : (ng/mL) 000 050