核桃壳纤维素降解FTIR特征.pdfVIP

第 44 卷 第 3 期 林 业 科 学 Vol44 , No3 2 0 0 8 年 3 月 SCIENTIA SILVAE SINICAE Mar. , 2 0 0 8 核桃壳纤维素降解的 FTIR 特征 1 1 ,2 1 1 邹局春 　郑志锋 　凌 　敏 　张宏健 ( 1 西南林学院木质科学与装饰工程学院　昆明650224 ; 2 东北林业大学材料科学与工程学院　哈尔滨 150040) ( ) 摘 　要 : 　以傅里叶红外光谱 FTIR 为分析手段 ,研究以苯酚为溶剂 、酸催化条件下核桃壳纤维素降解过程中其主 要化学基团特征随反应时间的变化 。结果表明:上述过程虽然可以用液化来描述 ,但本质上是核桃壳纤维素的降 解反应 ,纤维素分子链降解为低聚糖及葡萄糖等低分子物质 ,最终导致吡喃环开环 。 关键词 : 　核桃壳 ; 纤维素 ; 降解 ; FTIR ( ) 中图分类号 :TQ3521 　　　文献标识码 :A 　　　文章编号 :1001 - 7488 2008 03 - 0129 - 06 Degradation of Cellulose of Walnut Shell Based on FTIR Characteristics Zou Juchun1 　Zheng Zhifeng1 ,2 　Ling Min1 　Zhang Hongjian1 ( 1 Faculty of Wood Science and Decoration Engineering , Southwest Forestry University 　Kunming 650224 ; 2 Material Science and Engineering College , Northeast Forestry University 　Harbin 150040) Abstract : 　By means of FTIR , the cellulose of walnut shell was liquefied and degraded under acid catalyst in the presence of phenol firstly. The variation of main chemical groups of liquefied and degraded products of cellulose as a function of reaction time based on FTIR characteristics was discussed in this paper. Results from FTIR spectra showed , although the course of reaction could be described by liquefaction , the process was a degradation of cellulose essentially ; cellulose was degraded to low molecular fragments such as oligosaccharides , and the pyranoid ring was broken at last. Key wo