水压试验为何操纵氯离子含量(国外英文资料).docVIP

水压试验为何控制氯离子含量(国外英文资料)Why is the hydrostatic test controlling the concentration of chlorine ions at 25ppmThe passive metal still has a certain reaction capability, which is that the dissolution and repair of the passivated membrane are in dynamic equilibrium. When the medium contains active anions (common as chloride ions), the balance is destroyed and the solution is superior. The reason is that the chloride ion can preferentially selective adsorption on the passivation membrane, supplant oxygen atoms, and then and cation combined into soluble chloride in passivation membrane, the results of the base metal is shown in the new generated little corrosion pit on specific point (aperture in the 20 ~ 30 microns), these small pits called pitting corrosion, can also be understood as the corrosion hole generated active center. The presence of chlorine ions has a direct and destructive effect on stainless steel. Of the stainless steel sample to different concentrations of chloride ions in solution of constant potential method in measuring the potential and current relation curve of anode potential reaches a certain value, it can be seen that current density decreases, suddenly began to form stable passivation membrane, its resistance is high, and within the region (passivation area) by a certain potential. As the concentration of chloride ion increases, the critical current density increases, the primary passivating potential increases, and the area of passivation is narrowed. The explanation for this feature is in the passivation potential area, chloride ion competition with oxidizing substances, and into the film, the resulting lattice defects, reduce the resistivity of oxide. Therefore, in the presence of chlorine ion, it is not easy to be passivated, and it is not easy to maintain passivation.In a pressure vessel made of austenitic stainless steel, the presence of a chloride solution also causes a stress corrosion. This is due to the solution of chloride ions on the surf