超声波辅助共沉淀法制备大比表面积TiO2-Al2O3复合载体.pdfVIP

学兔兔 石 油 化 工 · 726· PETR0CHEMICAL TECHN0L0GY 2011年第4O卷第7期 超声波辅助共沉淀法制备大比表面积 TiO2一Al2 o3复合载体 彭会左，杨运泉，王威燕，何 兵，钦柏豪 (湘潭大学 化工学院，湖南 湘潭 411105) [摘要]分别以氨水、碳酸氢铵、尿素为沉淀剂，A1C13为铝源，采用超声波辅助共沉淀法制备了TiO 一AI O 复合载体；考察l『沉 淀剂对TiO2一A12O3复合载体结构性能的影响；采用FTIR、XRD、N2吸附一脱附法、SEM等手段埘所制得的复合载体进行了表征。 表征结果显示，TiO2一A12O3复合载体中TiO2为锐钛矿型，A12O3为^y—A12O3晶型，采用氨水和碳酸氢铵为沉淀剂提高了锐钛矿 TiO2的热稳定性，加入十六烷基三甲基溴化铵有利于增大载体的孔径和孔体积。其中以碳酸氢铵为沉淀剂制得的TiO，一AI，O 复合载体的结构性能最好，主要是因为碳酸氢铵是一种缓冲溶液，释放N啦的速率较慢，陔复合载体的 L径达30．9 nm、孔体积达 2．19 mL／g、比表面积达284 m ／g。 [关键词]二氧化钛一氧化铝复合载体；超声波；共沉淀法；催化剂载体 [文章编号]1000—8144(2011)07—0726—06 [中图分类号]TQ 426 65 [文献标识码1 A Preparation of TiO2-AI2 O3 Composite Support with High Specific Surface Area by Ultrasound--Assisted Co--Precipitation Method Peng Huizuo，Yang Yunquan，Wang WeiyaH，He Bing，Qin Bohao (College ofChemical Engineering，Xiangtan University，Xiangtan Hunan 4I1105，China) [Abstract]TiO2一A12 03 composite supports，which could be used in preparation of hydrorefining catalysts，were synthesized from A1C13 and NH4 HCO3(or NH3·H2O and(NH2)2 CO)as the precipitant by CO—precipitatibn method combined with ultrasonic dispersion．Effects of the precipitants on the properties of the TiO2-A12 O3 composite supports were studied．The products were characterized by means of FTIR，XRD，N2 adsorption—desorption and SEM．The results showed that TiO2 and A12 O3 in the TiO2-A12 O3 composite supports existed in the forms of anatase ph