醋酸甲酯加氢反应的热力学计算与分析.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第4期 PETR0CHEMICAL TECHN0L0GY ·409· 醋酸甲酯加氢反应的热力学计算与分析 孙成伟，郭翠梨，叶陈良，秦宏云 (天津大学化工学院，天津300072) [摘要]对醋酸甲酯加氢制乙醇反应体系进行了热力学分析。计算了各独立反应的标准摩尔反应吉布斯自由能，分析了温度、 压力、氢气与醋酸甲酯的摩尔比(氢酯比)对反应体系平衡组成的影响以及对醋酸甲酯转化率和乙醇选择性的影响。计算和分析 结果表明，各独立反应在423～723 K内的标准摩尔吉布斯自由能均大于0，没有适宜的压力和氢酯比反应将很难进行；较低的 温度有利于乙醇的生成和抑制副产物的产生，适宜的温度为423～550 K；在压力低于2．0 MPa时，醋酸甲酯转化率和乙醇选择 性均随压力的升高而快速增加，适宜的压力为2．0～3．0 MPa；在氢酯比低于1O时，醋酸甲酯转化率和乙醇选择性均随氢酯比 的增大而快速增加，适宜的氢酯比为1O～20。 [关键词]醋酸甲酯；加氢；乙醇；热力学分析；吉布斯自由能 【文章编号]1000—8144(2015)04—0409—06 [中图分类号]TQ 013．1 [文献标志码]A Thermodynamic Analysis for HydrOgenation of Methyl Acetate Sun Chengwei，Guo Cuili，Ye Chenliang，Qin Hongyun (The School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China) [Abstract]The thermodynamics of methyl acetate hydrogenation system was studied and the Gibbs free energies of the reactions in the system were calculated．The effects of temperature，pressure and the molar ratio of hydrogen to methyl acetate on the equilibrium composition，methyl acetate conver。 sion and ethanol selectivity were investigated．The results showed that the standard Gibbs free energies of aU the reactions were more than 0 when the reaction temperature was in the range of 423—723 K．SO the reactions should be carried out under suitable pressure and the appropriate molar ratio．Low temper‘ ature is beneficial to the production of ethanol and can inhibit the generation of by—products，and the suitable reaction temperature is in the range of 423——550 K．The conversion of methyl acetate and the selectivity to ethano1 quickly