高压聚乙烯装置料仓脱气数学模型.pdfVIP

学兔兔 0 ～术一 ～技一 ～业一 ～工一 石 油 化 工 2010年第39卷第5期 P rR0CHEMICAL TECHN0L0GY -533· 古 同 口臣 聚乙烯装置料仓脱气数学模型 石志俭 (中国石油化工股份有限公司 齐鲁分公司塑料厂，山东 淄博 255411) [摘要]以费克第二扩散定律为核心，结合非连续操作过程中聚乙烯颗粒的停留时间分布函数，推导出高压聚乙烯装置料仓脱气 数学模型。该模型可定量计算料仓脱气过程中的通风量、料仓出口乙烯含量和聚乙烯颗粒最小脱气时间。运用料仓脱气数学模 型可在料仓内一定初始乙烯含量下，预测出为使乙烯含量降低到某一标准所需的通风量以及达到安全生产要求所需的最小脱气 时间。料仓出口气体中乙烯含量的计算值与工业装置的实际值基本吻合，证明料仓脱气数学模型具有较高的准确度。该模型求 解过程简单，为料仓的安全运行、节约能源及优化操作提供了理论指导。 [关键词]高压聚乙烯；料仓脱气；数学模型；聚乙烯颗粒 [文章编号]1000—8144(2010)05—0533—04 [中图分类号]TQ 051．2 [文献标识码]A Mathematical Model for Purging Process of Silos in High-Pressure Polyethylene Plant Shf Zhijian (Qilu Branch Plastic Factory，SINOPEC，Zibo Shandong 25541 1，China) [Abstract]Based on the resident time distribution function of polyethylene particles in the silos of high—pressure polyethylene plant and Fick s second diffusion law，a mathematic model describing the purging process inside the silos was deduced to investigate the ethylene distributions and their variations versus time in the silos．This silo purging model can be used to quantitatively calculate purging air flow rate，outlet ethylene concentration and minimum residence time of polyethylene particles in the purging process．This model is particularly suitable for polyethylene industrial process due to its simple calculation．By using this model，mi nimum purging air flow rate under the given inlet ethylene concentration can be calculated and the minimum time which the purging process needs for safe operation can also be obtained．The comparison betw