高铁酸钾氧化去除水中三氯生的研究.pdfVIP

中国环境科学 2016,36(9) ：2665~2671 China Environmental Science 高铁酸钾氧化去除水中三氯生的研究 1* 1,2 2 1 1 3 1 李青松 ,金伟伟 ,马晓雁 ,李国新 ,陈国元 ,高乃云 ,廖文超 (1.厦门理工学院水资源环境研究所,福建 厦门 361024 ；2.浙江工业大学建筑工程学院,浙江 杭州 310014 ；3. 同济大学污染控制与资源化研究国家重点实验 室,上海 200092) 摘要：采用高铁酸钾对水中三氯生(TCS)的去除进行了研究, 探讨了 TCS 的降解机理,考察了高铁酸钾投加量、pH 值、天然有机物(NOM) 和双氧水等因素对 TCS 去除和中间产物 2,4-二氯苯酚(2,4-DCP)生成的影响.结果表明:TCS 通过醚键断裂降解生成 2,4-DCP,TCS 浓度为 550µg/L,高铁酸钾浓度为 15mg/L 时,600s 后 TCS 去除率可达 96.48%.增加高铁酸钾投加量可以提高 TCS 的去除,TCS 的去除率随 pH 值升 高呈现出降低的趋势,酸性环境有利于 TCS 的去除,pH 值为 4 时,TCS 的去除达 100%,腐殖酸和双氧水对 TCS 的去除有抑制作用.高铁酸钾 可以有效降解 TCS 并降低溶液的急毒性,降低水质健康风险. 关键词：三氯生；高铁酸钾；2,4-二氯苯酚；降解产物 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2016)09-2665-07 Study on the degradation of triclosan in aqueous by potassium ferrate. LI Qing-song1*, JIN Wei-wei1,2, MA Xiao-yan2 1 1 3 1 , LI Guo-xin , CHEN Guo-yuan , GAO Nai-yun , LIAO Wen-chao (1.Water Resources and Environmental Institute, Xiamen University of Technology, Xiamen 361005, China ；2.College of Civil Engineering and Architecture, Zhejiang University of Technology, Hangzhou 310014, China ；3.National Key Laboratory of Pollution Control and Reuse, Tongji University, Shanghai 200092, China). China Environmental Science, 2016,36(9)：2665~2671 Abstract ：The degradation of triclosan (TCS) in aqueous by potassium ferrate was investigated, and the degradation mechanism of TCS was researched. Besides, the effects of different factors, such as potassium ferrate dosage, TCS initial concentration, pH, natural organic matter (NOM) and hydrogen peroxide on TCS degradation and the 2,4-DCP formation during potassium ferrate oxidation was specifically discussed. The results indicated that TCS