环戊烯催化水合制备环戊醇的工艺研究.pdf

第40 卷 第2 期 河 北 工 业 大 学 学 报 20 11 年4 月 Vol.40 No.2 JOURNAL OF HEBEI UNIVERSITY OF TECHNOLOGY April 20 11 文章编号：1007-2373 (20 11) 02-0046-05 环戊烯催化水合制备环戊醇的工艺研究 孟祥瑜，陈霄榕，陈秀营 （河北工业大学 绿色化工与高效节能河北省重点实验室，天津 300130 ） 摘要 以环戊烯为原料，研究了强酸性树脂催化下直接法水合制备环戊醇的合成工艺．筛选了不同树脂催化剂， 考察了催化剂用量、反应物配比、反应温度、反应时间等反应条件对反应的影响，环戊烯水合最佳工艺条件为： 环戊烯与水的物质的量比为1 ∶6，苯酚与环戊烯的质量比为1 ∶1，催化剂DNW- Ⅱ用量是H O 质量的20 %，反 2 应温度为120 ℃，初始压力为1.50 MPa ，搅拌速度为600 r/min ，反应时间为4 h ．在上述工艺条件下具有工业化 应用潜力． 关 键 词 环戊烯；水合；环戊醇；溶剂；苯酚 中图分类号 TQ232 文献标志码 A Study on catalytic hydration of cyclopentene to cyclopantanol MENG Xiang-yu ，CHEN Xiao-rong ，CHEN Xiu-ying ( Provincial Key Laboratory of Green Chemical Engineering and High Efficiency Energy Saving, Hebei University of Technology, Tianj in 300 130, China ) Abstract In this paper, strong acid resins were used as the catalyst for preparation of cyclopentanol by direct hydration of cyclopentene. The influences of reaction conditions such as amount of catalyst, reactants ratio, reaction temperature and reaction time were examined and screened out from different resins. The best reaction conditions were as follows: molar ratio of cyclopentene to H O was 1 ∶6, mass ratio of phenol to cyclopentene was 1 ∶1, content of DNW- Ⅱ 2 was 20 % of the H O quality, the reactive temperature was 120 ℃, the initial pressure was 1.50 MPa, stirring speed 2