典型单环和双环芳烃加氢热力学.pdf

1 2 1 1 HSCChemistry4.0 100400 3 1000 8144201306 0625 07 TQ 031.4 A - - Hou Chaopeng 1 Li Yongdan2 Xia Guofu 1 Li Mingfeng 1 1. SINOPEC Research Institute of Petroleum ProcessingBeijing 100083China 2. School of Chemical EngineeringTianjin UniversityTianjin 300072China The hydrogenation of typical monocyclic and dicyclic aromatics was discussed by thermodynamic equilibrium calculation based on HSC-Chemistry4.0 database software. With temperature rise in the range of 100400 the Gibbs free energies of the aromatic hydrogenation reactions increase approximately linearlywhile their reaction equilibrium constants decrease. The effects of temperaturepressure and reactant composition on the conversion of the aromatics were investigated. Increasing the reaction system pressure and the mole ratio of hydrogen to hydrocarbon is propitious to the equilibrium conversion in the hydrogenation of benzene to cyclohexane at certain temperature. The influences of temperature and pressure on the equilibrium composition in the reaction system of naphthalene hydrogenation were also studied. aromatic hydrogenation monocyclic aromatics dicyclic aromatics thermodynamics benzene naphthalene /