掺钒TiO2薄膜光催化降解甲醛的影响因素研究_王淑勤_付鹏.pdf

第37 卷 第2 期 Vol. 37 No.2 第2 期 2014 年2 月 Environmental Science Technology Feb. 2014 王淑勤，付鹏.掺钒TiO薄膜光催化降解甲醛的影响因素研究 2 掺钒TiO薄膜光催化降解甲醛的影响因素研究 2 王淑勤， 付鹏 （华北电力大学环境科学与工程学院，河北 保定 071003） 摘 要：以毛玻璃片为载体，采用溶胶-凝胶法制备掺钒TiO 薄膜。用X 射线衍射（XRD）对钒掺杂TiO 与未掺杂TiO 进行表征。考 2 2 2 察不同反应条件及制备条件下TiO2 薄膜在可见光下对甲醛的催化活性的影响，并对TiO2 薄膜光催化降解甲醛的反应动力学进行研究。 结果表明，掺钒1% ，煅烧温度700 ℃，煅烧3 h 制得的TiO2 薄膜，在通氧情况下0.8 g/毛玻璃片负载量对碱性甲醛溶液的催化活性较好， 并且甲醛的降解反应能够较好地符合Langmuir-Hinshelwood 一级动力学规律。 关键词：钒掺杂TiO2 ；薄膜； 甲醛； 光催化； 动力学 中图分类号：X703.1 文献标志码：A doi ：10.3969/j.issn.1003-6504.2014.02.025 文章编号：1003-6504(2014)02-0129-05 Influencing Factors of V-doped Titanium Films on Formaldehyde Photocatalytic Degradation WANG Shuqin ， FU Peng （School of Environmental Science and Engineering ，North China Electric Power University ，Baoding 071003 ，China） Abstract ：V-doped TiO -coated thin films were prepared by sol-gel method using frosted glass plate as the carrier. The V- 2 doped TiO2 and the undoped TiO2 were characterized by X-ray diffraction. Effects of different reaction conditions ，as well as preparation conditions on the performance of film for photocatalytic degradation of formaldehyde under visible light were investigated ，and kinetics of photocatalytic degradation of formaldehyde by V-doped TiO2 film was studied. Results showed that 0.8 g loading TiO2 prepared by 1% doped vanadium and calcined at temperature o