结构变化对梯度互穿网络聚合物力学性能影响的研究_穆中国.pdfVIP

134 材料导报 2008 年10 月第22 卷第10 期 1, 3 2 穆中国 , 王源升 ( 1 , 430033; 2 , 116018; 3 , 430033) 设计了一种新的梯度组分分布数学模型, 采用梯度因子和梯度层数控制梯度组分的分布, 研 了梯度 结构变化对梯度IPNs 力学性能的影响结果表明, 梯度层数越多, 梯度IPNs 的拉伸性能和抗冲击性能越优异, 随着 梯度因子的增加, 梯度IPNs 的拉伸性能先平缓增加, 当梯度因子过高时, 梯度IPNs 的拉伸性能显著下降, 梯度 IPNs 的抗冲击性能随着梯度因子先显著增加, 然后平缓变化梯度IPNs 的力学性能优于普通 IPNs IPNs : T Q316. 6 : A Study on Effect of Structure Variation on Mechanical Property of Graded Interpenetrating Ploymer Networks(IPNs) MU Zhongguo1, 3 , WANG Yu nsheng2 ( 1 Dep rtment of B sic Courses, N v l University of Engineering , Wuh n 430033; 2 Antichemistry L bor tory , D li n N v l Ac demy , D li n 1160 18; 3 Administr tive Office of T r ining , N v l University of Engineering, Wuh n 430033) A stract A new m them t ic model w s dopted t o design the distribution of gr ded component in gr ded IPNs, Bot h gr ded l yers number nd gr ded f ctor were used to control the dist ribution of gr ded component. the effect of gr ded structure on mech nic l properties w s studied, The results indic te th t both t ensile property nd imp ct prop- erty enh nce gr du lly with Incre se of number of gr ded l yer . T ensile property prim rily decre ses w ith gr ded f c- tor, w hen gr ded f ctor v lue is too high, t ensile property of gr ded IPNs decre ses quickly. Imp ct property of gr ded IPNs prim rily incre se w ith incre se of gr ded f ctor sh rply. Then it ch nge gently . Mech nic l property of gr ded IPNs is superior to those of ordin ry IPNs. Key words polyureth ne, epoxy resin, gr ded IPNs, tensile property , im p ct propert y 0