煤中汞赋存形态及其热解时析出规律研究.pdfVIP

第42卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No.2 2014年2月 Journal of Fuel Chemistry and Technology Feb. 2014 文章编号:0253鄄2409(2014)02鄄0146鄄04 煤中汞赋存形态及其热解时析出规律研究 王摇 鹏,董摇 勇,喻摇 敏,崔摇 琳,张立强 (山东大学 燃煤污染物减排国家工程实验室,山东 济南摇 250061) 摘摇 要:利用程序升温热解反应系统,研究了煤中不同形态汞的析出温度,通过积分各析出温度下汞的总析出量来分析各赋 存形态的汞所占比例,同时研究了添加CaCl 后抑制煤热解过程中汞析出的机理。 结果表明,实验所选煤中汞主要存在三种 2 赋存形态,其析出温度点分别在220、300 和400 益;其中,300 益析出的汞所占比例最高,为54.18%,从析出温度分析该部分 汞主要以HgS的形式赋存。 添加CaCl 对第一和第三赋存形态的汞析出具有抑制作用,改变了其析出温度,对第二赋存形态 2 的汞析出几乎无影响,添加后使得汞析出温度更为集中;抑制析出的主要原因是氧化吸附,添加CaCl 对汞总析出量基本无 2 影响。 关键词:汞;煤;赋存形态;析出规律 中图分类号:TQ534摇 摇 文献标识码:A Mercury occurrence mode in coal and its release behavior during pyrolysis WANG Peng,DONG Yong,YU Min,CUI Lin,ZHANG Li鄄qiang (National Engineering Laboratoryfor Coal鄄fired Pollutants EmissionReduction,Shandong University,Jinan摇 250061,China) Abstract:A temperature鄄programmedtubefurnacewassetuptoinvestigatetheoccurrencemodesofmercuryin coal according to its releasing temperature during pyrolysis. The fraction of mercury in each occurrence mode was determined by calculating the total released amount at different temperature ranges. The mechanism of mercury release inhabitation by CaCl was studied as well. The result showed that there are mainly three 2 occurrence modes of mercury in coal:their release temperatures are 220,300 and400 益.The secondary mode released at 300 益 takes54.18%,which should be HgSaccording to its decomposition temperature. The CaCl2 inhibited the release of mercury at220 and400 益. The inhabitation ismainly caused by mercury oxidation and adso