Li3V2(PO4)3掺锰的改性研究.pdfVIP

L．3V2(P04)3掺锰的改性研究 刘云霞一，朱先军2，詹晖1，周运鸿1 (1．武汉大学化学与分子科学院，湖北武汉430079；2．华巾师范大学化学学院。湖北武汉430079) 同的结构，均属单斜晶系P2，，n。且随着锰含量的增加，样品的颗粒变大。循环伏安和充放电测试结果表明。随着锰含量 环性能。 关键词：Li3V2(P04)。；锰掺杂；溶胶凝胶法：电化学性能 912．9 中图分类号：TM 文献标识码：A 文章编号：1002—087 X(2011)02一0173—03 onmodificationof Mn Study Li3V2(P04)3by doping LIU Yun-xial，ZI-IUXian-jtm2,ZHANHuil，ZHOUYun-hon91 andMolecular Hubei (1．CollegeofChemistry Sciences,WuhanUniversity,Wuhan430079，China； ChinaNormal Hubei 2．ChemistryCollege,Central 430079,Ch／na) University,Wuhan cathodematenals Abstract：Li-ion battery U洲nA，2_。(P04)3(艋0，0．05，0．1O，0．20)weresynthesizedbysol-gel method．Thestructureand of werecharacterized morphologysamples byX-raydiffraction(XRD)andscanning electron electrochemicalbehaviorswerecharacterized microscopy(SEM)．The bygalvanostaticcharge／discharge and resultsshowthatthe sizeof areincreased smallamount voltammetry．The cyclic particle products byadding ofMnin the structuredoesnot with withoutMn2+．Theinitialca— Li3V2(P04)3，butcrystal changedcomparingLi3v2(P04)3 of decreaseswiththeMncontent amore pacityLi洲nN2_x(P04)3 increasing，however，Li31Mn01V。(P04)3displays stable than indicatesthatasmallmountofMn can