Tb3+Eu3+共掺杂CaMoO4荧光粉在防伪技术领域应用-.PDFVIP

Applied Physics 应用物理, 2015, 5(12), 181-187 Published Online December 2015 in Hans. /journal/app /10.12677/app.2015.512025 The Application of Tb3+/Eu3+ Codoped CaMoO4 Phosphors in the Field of Anti-Counterfeiting Technology Jianhui Xiong Key Laboratory of Photonic and Electronic Bandgap Material Ministry of Education, Harbin Normal University, Harbin Heilongjiang th th th Received: Dec. 8 , 2015; accepted: Dec. 26 , 2015; published: Dec. 29 , 2015 Copyright © 2015 by author and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract Series of CaMoO : Tb3+, Eu3+ phosphors were prepared by the method of precipitation. The struc- 4 ture and morphology of the phosphors were characterized by the X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM). The photoluminescence properties of the pre- pared products were researched, find the energy can transfer from Tb3+ to Eu3+. Calculated the color coordinates of the phosphors under the excitation of 274 nm, 394.5 nm and 486 nm, by cal- culating and comparing the standard deviation of the color coordinates, when the concentration is 5% Tb3+, 0.5% Eu3+, the standard deviation of the color coordinates is the maximum. Illustrating the doping concentrations of phosphor color change with excitation wavelength is the most obvious. It is indicated that the fluorescent powder may be used in the field of anti-counterfeiting technology. Keywords Tb3+, Eu3+, Anti-Counterfeiting Technology, Energy Transfer Tb3+/Eu3+共掺杂的CaMoO 荧光粉在防伪技术 4