镁离子存在下乙醇-水混合溶液中碳酸钙结晶行为研究.PDFVIP

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第7 期, 623～628 ACTA CHIMICA SINICA No. 7, 623～628 ·研究论文· 镁离子存在下乙醇-水混合溶液中碳酸钙结晶行为的研究 岳林海*,a 贾志刚a 金达莱a,b 郑遗凡c 徐铸德*,a a ( 浙江大学化学系 杭州 310027) (b 浙江理工大学机械与自动控制学院 杭州 310018) (c 浙江工业大学化学工程与材料学院 杭州 310014) 摘要 通过对不同反应体系中合成样品的物相及镁含量变化规律的分析, 认为水溶液中碳酸钙的结晶遵循溶解重结晶 机理, 乙醇-水溶液中则以聚集重构为主, 碳酸根阴离子的溶剂化作用对碳酸钙的沉积产生显著影响. 采用XRD, IR 等 手段对醇水混合溶液中合成的碳酸钙样品进行分析, 认为形成了含镁方解石及具有类白云石结构的过渡相同时存在的 混合物相, 醇水溶液中含镁方解石趋于白云石化. 关键词 碳酸钙; 溶剂化作用; 溶解重结晶; 聚集重构 Study on the Crystallization Behavior of Calcium Carbonate in Ethanol-Water Mixed Solution in the Presence of Mg2＋ YUE, Lin-Hai*,a JIA, Zhi-Ganga JIN, Da-Laia,b ZHENG, Yi-Fanc XU, Zhu-De*,a (a Chemisty Department, Zhejiang University, Hangzhou 310027) (b Machine and Automation Department , Zhejiang Science-Technology University, Hangzhou 310018) (c College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310014) Abstract Through the analysis of phase and Mg content variation of samples obtained from different reac- tion system, we propose that the crystallization of calcium carbonate was mainly the aggregation-mediated process in the ethanol-water mixed solution and the solution-mediated process only in aqueous solution. Solvation of CO2－ had obvious influence on the deposition of calcium carbonate. According to XRD and 3 IR of deposits, it was considered that mixed phases of Mg calcite and a transit