焦磷锆钛的合成及其对铯离子的吸附性能.pdfVIP

and other cations in the same concentration respectively. However, as the concentration of sodium ions is more than 100 times than the cesium ion in solution, the adsorption capacity of ZTPP decrease significantly. The removal rate of cesium ion can reach approximately 100% by adding more material . Ammonium chloride solution with concentration of 4 mol/L can be used as eluent and desorption experiments demonstrate that cesium can be washed out from ZTPP effectively. On the whole, adsorption experiments results show that zirconium titanium pyrophosphate have such characterizations as good thermal stability, high removal rate of cesium ion, high adsorption speed and adsorption capacities. It can be used as absorbent to remove cesium ion quickly and effectively in water which has a promising prospect in radionuclide contamination emergency treatment. KEY WORDS ：Cesium ion, Phosphate, Ion exchange, Adsorption 目 录 第一章 文献综述 1 1.1 铯的性质 1 1.2 无机离子交换剂去除水溶液中铯 1 1.2.1 硫属化合物 2 1.2.2 沸石 2 1.2.3 不溶性亚铁氰化物 4 1.2.4 硅钛化合物 5 1.2.5 多价金属磷酸盐 6 1.2.6 杂多酸化合物 7 1.3 离子交换基本原理 8 1.4 离子交换理论学说 9 1.5 影响离子交换能力的因素 10 1.6 放射性废水离子交换处理 10 1.7 课题研究意义及主要工作 11 第二章 实验方法 13 2.1 实验设备及主要试剂 13 2.1.1 实验设备 13 2.1.2 主要试剂 13 2.2 铯离子检测方法的建立 14 2.2.1 消电离剂的选择 14 2.2.2 标准工作曲线的建立及样品浓度测定 14 2.3 焦磷锆钛的合成 15 2.3.1 Ti-前驱体液的制备 15 2.3.2 焦磷锆钛的制备 15 2.3.3 焦磷